Isolation of [1]ruthenocenophanes: Synthesis of polyruthenocenylstannanes by ring-opening polymerization

被引：54

作者：

Vogel, U ^{[1
]}

Lough, AJ ^{[1
]}

Manners, I ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 25期

关键词：

cyclopentadienyl ligands; ring-opening polymerization; ruthenium; stannanes; strained molecules;

D O I：

10.1002/anie.200454022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Strained, ring-tilted [1]ruthenocenophanes 1 have been prepared for the first time. Ring-opening polymerization (ROP) of an example of 1 with a Sn bridge affords a novel, bimetallic, high-molecular-weight polyruthenocenylstannane 2 (R= mesityl).

引用

页码：3321 / 3325

页数：5

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