High-spin molecules: A mixed-valence Mn6 octahedron with an S=11 ground state

被引：14
作者：
Stamatatos, Theocharis C. [1 ]
Pringouri, Konstantina V. [1 ]
Abboud, Khalil A. [1 ]
Christou, George [1 ]
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
来源：
POLYHEDRON | 2009年 / 28卷 / 9-10期
基金：
美国国家科学基金会;
关键词：
Mixed-valence manganese clusters; 1,1,1-Tris(hydroxymethyl)ethane; Magnetochemistry; High-spin molecules; Octahedral topology; ALKOXIDE ANION CLUSTERS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; COMPLEX; HEXANUCLEAR; IRON(III);
D O I：
10.1016/j.poly.2008.10.031
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The employment of 1,1,1-tris(hydroxymethyl)ethane ligand in higher oxidation state Mn cluster chemistry has yielded a new hexanuclear, mixed-valence (II,III,IV) compound with a rare [Mn-6(mu(6)-O)](18+) octahedral core. The Mn6 molecule is completely ferromagnetically coupled and possesses an S = 11 ground state, the maximum for a Mn-II, 2Mn(III), 3Mn(IV) species. (C)2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1624 / 1627
页数：4
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