Modulating CO2 Adsorption in Metal Organic Frameworks via Metal-Ion Doping

被引：29
作者：
Cui, Ping [3 ]
Li, Ji-Jing [1 ,2 ]
Dong, Jie [1 ,2 ]
Zhao, Bin [1 ,2 ]
机构：
[1] Nankai Univ, Key Lab Adv Energy Mat Chem, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Coinnovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
[3] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China
来源：
INORGANIC CHEMISTRY | 2018年 / 57卷 / 10期
关键词：
PHOTOCATALYTIC DEGRADATION; UPTAKE CAPACITY; GAS-ADSORPTION; ENHANCED CO2; CAPTURE; DESIGN; H-2; FUNCTIONALIZATION; SEPARATION; ADSORBENTS;
D O I：
10.1021/acs.inorgchem.8b00730
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
One novel metal organic framework {[Ni-6(OH)(4)(BTB)(8/3)(H2O)(6)]center dot 4H(2)O center dot 9DMF}(n) (DMF = dimethylformamide) based on 1,3,5-benzenetribenzoic acid (H3BTB) was successfully synthesized under basic condition at room temperature, featuring a unique twofold interpenetrated pcu-type net with [Ni-6(OH)(4)(COO)(8-)(H2O)(6)] cluster as building block. Its gas-adsorption behaviors were investigated and modified by utilizing metal(II)-doped procedure, which was certified to be a highly effective pathway in enhancing CO2 uptake capacity.
引用
收藏
页码：6135 / 6141
页数：7
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