Iodine-Catalyzed Suzuki-Miyaura Coupling Performed in Air

被引：48
|
作者：
Mao, Jincheng [1 ]
Hua, Qiongqiong [2 ]
Xie, Guanlei [1 ]
Guo, Jun [1 ]
Yao, Zhigang [3 ]
Shi, Daqing [1 ]
Ji, Shunjun [1 ]
机构：
[1] Suzhou Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China
[2] Xuzhou Normal Univ, Dept Chem, Xuzhou 221116, Jiangsu, Peoples R China
[3] Suzhou Univ, Analyt & Testing Ctr, Suzhou 215123, Jiangsu, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 04期
基金：
中国国家自然科学基金;
关键词：
accelerating effect; arylboronic acids; cross-coupling reactions; iodine; polyethylene glycol 400 (PEG-400); HIGHLY EFFICIENT; ARYL CHLORIDES; PALLADIUM NANOPARTICLES; ORGANOBORON DERIVATIVES; ASYMMETRIC-SYNTHESIS; CROSS-COUPLINGS; LIGAND; BIARYLS; GENERATION; OXIDATION;
D O I：
10.1002/adsc.200800624
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Suzuki-type coupling reactions can be performed directly in air using a catalytic system composed of iodine, potassium carbonate, and polyethylene glycol 400 (I-2/K2CO3/PEG-400). Iodine was found to be an effective additive for accelerating these couplings. The methodology is also suitable for the coupling of (E)-beta-bromostyene with phenylboronic acid, with retention of the double bond geometry.
引用
收藏
页码：635 / 641
页数：7
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