Mechanism of chain photochemical reaction of (n-Bu4N)2[PtCl6] in chloroform

被引：8

作者：

Matveeva, Svetlana G. ^{[1
]}

Grivin, Vjacheslav P. ^{[1
]}

Plyusnin, Victor F. ^{[1
,2
]}

Vasilchenko, Danila B. ^{[2
,3
]}

Glebov, Evgeni M. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Voevodsky Inst Chem Kinet & Combust, Siberian Branch, 3 Inst Skaya Str, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, 3 Inst Skaya Str, Novosibirsk 630090, Russia

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2018年 / 359卷

基金：

俄罗斯科学基金会;

关键词：

Photochemistry; Platinum(IV) complexes; Chloroform; Photosolvation; Chain photochemical reactions; Laser flash photolysis; SOLVENT-INITIATED PHOTOCHEMISTRY; PTCL62-COMPLEX; FLASH-PHOTOLYSIS; PHOTOREDUCTION; REDUCTION; CHLORIDE; HEXACHLOROPLATINATE(IV); PHOTOOXIDATION; METHANOL; PHOTOSUBSTITUTION;

D O I：

10.1016/j.jphotochem.2018.03.038

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photochemistry of the (n-Bu4N)(2)[PtCl6] complex in chloroform was studied by means of stationary photolysis and nanosecond laser flash photolysis. The results were explained in the framework of the chain photosolvation. The chain character of photolysis was supported by the quantum yield dependencies on the concentration of the initial complex and light intensity. Spectra of two successive Pt(III) intermediates were registered, their spectral and kinetic characteristics were determined. Based on the obtained experimental data, the literature mechanism of photolysis was revised. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：80 / 86

页数：7

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