Solid-State Scrolls from Hierarchical Self-Assembly of T-Shaped Rod-Coil Molecules

被引：56

作者：

Hong, Dong-Je ^{[1
,2
]}

Lee, Eunji ^{[1
,2
]}

Jeong, Haemi ^{[1
,2
]}

Lee, Jeong-kyu ^{[3
]}

Zin, Wang-Cheol ^{[3
]}

Nguyen, Trung Dac ^{[4
,5
]}

Glotzer, Sharon C. ^{[4
,5
]}

Lee, Myongsoo ^{[1
,2
]}

机构：

[1] Yonsei Univ, Ctr Supramol Nanoassembly, Seoul 120749, South Korea

[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

[3] Pohang Univ Sci & Technol, Polymer Res Inst, Dept Mat Sci & Engn, Pohang 790784, South Korea

[4] Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA

[5] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 09期

关键词：

amphiphiles; liquid crystals; nanostructures; self-assembly; TUBULAR PHASE; NANOTUBES; MEMBRANES; NANOTECHNOLOGY; NANORODS;

D O I：

10.1002/anie.200804307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) On a roll: Attachment of flexible coils to the middle of a rigid rod generates T-shaped rod-coil molecules that self-assemble into layers that roll up to form filled cylindrical and hollow tubular scrolls, depending on the coil length, in the solid state (see picture); the rods are arranged parallel to the layer plane. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1664 / 1668

页数：5

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