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Solid-State Scrolls from Hierarchical Self-Assembly of T-Shaped Rod-Coil Molecules
被引:56
|作者:
Hong, Dong-Je
[1
,2
]
Lee, Eunji
[1
,2
]
Jeong, Haemi
[1
,2
]
Lee, Jeong-kyu
[3
]
Zin, Wang-Cheol
[3
]
Nguyen, Trung Dac
[4
,5
]
Glotzer, Sharon C.
[4
,5
]
Lee, Myongsoo
[1
,2
]
机构:
[1] Yonsei Univ, Ctr Supramol Nanoassembly, Seoul 120749, South Korea
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
[3] Pohang Univ Sci & Technol, Polymer Res Inst, Dept Mat Sci & Engn, Pohang 790784, South Korea
[4] Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA
[5] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
关键词:
amphiphiles;
liquid crystals;
nanostructures;
self-assembly;
TUBULAR PHASE;
NANOTUBES;
MEMBRANES;
NANOTECHNOLOGY;
NANORODS;
D O I:
10.1002/anie.200804307
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
(Figure Presented) On a roll: Attachment of flexible coils to the middle of a rigid rod generates T-shaped rod-coil molecules that self-assemble into layers that roll up to form filled cylindrical and hollow tubular scrolls, depending on the coil length, in the solid state (see picture); the rods are arranged parallel to the layer plane. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码:1664 / 1668
页数:5
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