The [bis(η5-cyclopentadienyl)titanium(IV)-bis(L-methionine)] dichloride

被引：7

作者：

Bína, R

Císarová, I

Pavlista, M

Pavlík, I

机构：

[1] Univ Pardubice, Res Ctr New Inorgan Cpds & Adv Mat, Pardubice 53210, Czech Republic

[2] Charles Univ, Fac Nat Sci, Prague 12843, Czech Republic

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2004年 / 18卷 / 06期

关键词：

titanocene dichloride; alpha-amino acids;

D O I：

10.1002/aoc.623

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The structure of ionic complex [Cp2Ti(L-Met)(2)](2+) [Cl-](2) (where Cp = eta(5)-C5H5) possessing C-2 symmetry is presented. Discrete cationic units with distorted tetrahedral geometry around the central titanium atom are connected through intermolecular (HCl)-Cl-... bonds between ammonium group protons of alpha-amino acid ligands and chloride anions. Copyright (C) 2004 John Wiley Sons, Ltd.

引用

页码：262 / 263

页数：2

共 6 条

[1] STRUCTURAL STUDIES OF (PI-C5H5)2MX2 COMPLEXES AND THEIR DERIVATIVES - STRUCTURE OF BIS(PI-CYCLOPENTADIENYL)TITANIUM DICHLORIDE [J].