Synthesis and Structural Characterization of Diiron Dithiolate Complex [(μSCH2)2NCH2PhFe2(CO)5][(η5-Ph2PC5H4)2Fe] Containing Diphosphine Ligand

被引：2
|
作者：
Gao, Wei [1 ]
Zhang, Jing-Yu [1 ]
Yang, Jing [1 ]
机构：
[1] Henan Univ Tradit Chinese Med, Sch Pharm, Zhengzhou 450046, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 07期
关键词：
Diiron dithiolate; 1,1'-bis(Diphenylphosphino)-ferrocene; Synthesis; Characterization; CRYSTAL-STRUCTURE; ACTIVE-SITE; AZADITHIOLATE COMPLEXES; BIOLOGICAL-ACTIVITY; PROPANEDITHIOLATE COMPLEX; DFT CALCULATION; HYDROGENASE; MODELS;
D O I：
10.14233/ajchem.2014.16183B
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel diiron dithiolate complex n[(mu-SCH2)(2)NCH2PhFe2(CO)](5)[eta(5)-Ph2PC5H4)Fe] (1); as the active site of WeFel-hydrogenases, has been prepared and structurally characterized. The title complek was prepared by treatment of [(mu=SCH2)(2)NCH2Ph]Fe-2(CO)(6) (A) with 1,1- (diphenylphosphino)-ferrocene (DPPF) [(eta(5)-Ph2PC5H4)(2)Fe] in the presence of Me3NO center dot 2H(2)O-in MeCNIat room temperature in 53 To yield. The new complex 1 was characterized by IR, H-1 NMR, (31) P NMR and C-13 NMR spectroscopy.
引用
收藏
页码：2089 / 2091
页数：3
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