Zeolitic Imidazolate Frameworks: Synthesis, Functionalization, and Catalytic/Adsorption Applications

被引:149
作者
Bhattacharjee, Samiran [1 ]
Jang, Min-Seok [1 ]
Kwon, Hee-Jin [1 ]
Ahn, Wha-Seung [1 ]
机构
[1] Inha Univ, Dept Chem & Chem Engn, Inchon 402751, South Korea
基金
新加坡国家研究基金会;
关键词
Zeolitic imidazolate frameworks (ZIFs); ZIF-8; Synthesis; Functionalization; Heterogeneous catalysis; Adsorption; METAL-ORGANIC FRAMEWORKS; ROOM-TEMPERATURE SYNTHESIS; CORE-SHELL MICROSPHERES; CARBON-DIOXIDE CAPTURE; IONOTHERMAL SYNTHESIS; ZIF-8; NANOPARTICLES; WATER-ADSORPTION; DRY-GEL; CO2; MEMBRANE;
D O I
10.1007/s10563-014-9169-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Zeolitic imidazolate frameworks (ZIFs) are comprised of transition metal ions (Zn, Co) and a range of imidazolate linkers in a tetrahedral coordination similar to that in crystalline aluminosilicate zeolites. The high surface area, tunable nanoporosity that can be subject to functionalization and the excellent thermal/chemical stability of ZIFs are attractive for heterogeneous catalysis and selective gas adsorption/separation. This review presents the current trends in synthesis, surface modification and catalytic reactions/adsorption of ZIF-based materials with particular emphasis on ZIF-8, which is the most widely studied structure among ZIFs.
引用
收藏
页码:101 / 127
页数:27
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