Transfer hydrodehalogenation of organic halides catalyzed by water soluble ruthenium(II) phosphine complexes

被引：29

作者：

Benyei, AC

Lehel, S

Joo, F

机构：

[1] Institute of Physical Chemistry, Lajos Kossuth University, H-4010 Debrecen

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 116卷 / 03期

基金：

匈牙利科学研究基金会;

关键词：

hydrodehalogenation; hydrogen transfer reaction; sodium formate; ruthenium; water soluble phosphines;

D O I：

10.1016/S1381-1169(96)00369-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

C-X bonds in carbon tetrachloride, chloroform and 1-hexyl halogenides were transformed into C-H bonds in a transfer hydrodehalogenation reaction catalyzed by water soluble ruthenium(II) phosphine complexes. A turnover frequency of up to 1000 h(-1) can be achieved when an aqueous solution of sodium formate is the hydrogen donor and RuCl2(TPPMS)(2) (1) the catalyst (TPPMS = m-sulfophenyl diphenylphosphine sodium salt).

引用

收藏

页码：349 / 354

页数：6

相关论文

共 45 条

[1] THE RELATIVE AFFINITIES OF CO-ORDINATING ATOMS FOR SILVER ION .2. NITROGEN, PHOSPHORUS, AND ARSENIC [J].

AHRLAND, S ;

CHATT, J ;

DAVIES, NR ;

WILLIAMS, AA .

JOURNAL OF THE CHEMICAL SOCIETY, 1958, (JAN) :276-288

[2] HOMOGENEOUS METAL-CATALYZED HYDROGENOLYSIS OF C-F BONDS [J].

AIZENBERG, M ;

MILSTEIN, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (33) :8674-8675

[3] THE INVENTION OF RADICAL REACTIONS .32. RADICAL DEOXYGENATIONS, DEHALOGENATIONS, AND DEAMINATIONS WITH DIALKYL PHOSPHITES AND HYPOPHOSPHOROUS ACID AS HYDROGEN SOURCES [J].

BARTON, DHR ;

JANG, DO ;

JASZBERENYI, JC .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (24) :6838-6842

[4] ORGANOMETALLIC CATALYSIS IN AQUEOUS-SOLUTIONS - THE BIPHASIC TRANSFER HYDROGENATION OF ALDEHYDES CATALYZED BY WATER-SOLUBLE PHOSPHINE COMPLEXES OF RUTHENIUM, RHODIUM AND IRIDIUM [J].

BENYEI, A ;

JOO, F .

JOURNAL OF MOLECULAR CATALYSIS, 1990, 58 (02) :151-163

[5] A MODIFIED SYNTHESIS OF RUTHENIUM(II) HEXAAQUA SALTS [J].

BERNHARD, P ;

BINER, M ;

LUDI, A .

POLYHEDRON, 1990, 9 (08) :1095-1097

[6]

CHALONER PA, 1994, CATALYSIS METAL COMP

[7]

DAIGLE DJ, 1974, J HETEROCYCLIC CHEM, V17, P407

[8] WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .4. CATALYTIC-HYDROGENATION OF ALDEHYDES IN AN AQUEOUS 2-PHASE SOLVENT SYSTEM USING A 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEX OF RUTHENIUM [J].

DARENSBOURG, DJ ;

JOO, F ;

KANNISTO, M ;

KATHO, A ;

REIBENSPIES, JH ;

DAIGLE, DJ .

INORGANIC CHEMISTRY, 1994, 33 (02) :200-208

[9] INTERCONVERSION OF CHLOROFLUOROCARBONS IN PLASMAS [J].

DEAM, RT ;

DAYAL, AR ;

MCALLISTER, T ;

MUNDY, AE ;

WESTERN, RJ ;

BESLEY, LM ;

FARMER, AJD ;

HORRIGAN, EC ;

MURPHY, AB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (03) :347-348

[10] THERMAL GAS-PHASE HYDRODEHALOGENATION OF BROMOCHLORODIFLUOROMETHANE [J].

DELIJSER, HJP ;

LOUW, R ;

MULDER, P .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (01) :139-145

← 1 2 3 4 5 →