Cavity-enhanced ultrafast two-dimensional spectroscopy using higher order modes

被引：14
作者：
Allison, Thomas K. [1 ]
机构：
[1] SUNY Stony Brook, Stony Brook, NY 11794 USA
来源：
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS | 2017年 / 50卷 / 04期
基金：
美国国家科学基金会;
关键词：
ultrafast spectroscopy; frequency combs; cavity-enhanced spectroscopy; FREQUENCY COMB SPECTROSCOPY; EXCITED-STATE DYNAMICS; INFRARED-SPECTROSCOPY; LASER SPECTROSCOPY; TIME; CLUSTERS; WATER; INTERFEROMETER; TECHNOLOGY; VIBRATIONS;
D O I：
10.1088/1361-6455/50/4/044004
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
We describe methods using frequency combs and optical resonators for recording two-dimensional (2D) ultrafast spectroscopy signals with high sensitivity. By coupling multiple frequency combs to higher-order modes of one or more optical cavities, background-free, cavity-enhanced 2D spectroscopy signals are naturally generated via phase cycling. As in cavity-enhanced ultrafast transient absorption spectroscopy, the signal to noise is enhanced by a factor proportional to the cavity finesse squared, so even using cavities of modest finesse, a very high sensitivity is expected, enabling ultrafast 2D spectroscopy experiments in dilute molecular beams.
引用
收藏
页数：10
相关论文
共 64 条
[1]   Cavity-Enhanced Direct Frequency Comb Spectroscopy: Technology and Applications [J].
Adler, Florian ;
Thorpe, Michael J. ;
Cossel, Kevin C. ;
Ye, Jun .
ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 3, 2010, 3 :175-205
[2]   Ultrafast internal conversion in ethylene. II. Mechanisms and pathways for quenching and hydrogen elimination [J].
Allison, T. K. ;
Tao, H. ;
Glover, W. J. ;
Wright, T. W. ;
Stooke, A. M. ;
Khurmi, C. ;
van Tilborg, J. ;
Liu, Y. ;
Falcone, R. W. ;
Martinez, T. J. ;
Belkacem, A. .
JOURNAL OF CHEMICAL PHYSICS, 2012, 136 (12)
[3]  
[Anonymous], 1988, Atomicand Molecular Beam Methods
[4]   Spectroscopic Studies of Cryptophyte Light Harvesting Proteins: Vibrations and Coherent Oscillations [J].
Arpin, Paul C. ;
Turner, Daniel B. ;
McClure, Scott D. ;
Jumper, Chanelle C. ;
Mirkovic, Tihana ;
Challa, J. Reddy ;
Lee, Joohyun ;
Teng, Chang Ying ;
Green, Beverley R. ;
Wilk, Krystyna E. ;
Curmi, Paul M. G. ;
Hoef-Emden, Kerstin ;
McCamant, David W. ;
Scholes, Gregory D. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (31) :10025-10034
[5]   Two-dimensional infrared spectroscopy of peptides by phase-controlled femtosecond vibrational photon echoes [J].
Asplund, MC ;
Zanni, MT ;
Hochstrasser, RM .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2000, 97 (15) :8219-8224
[6]  
Benko C, 2014, NAT PHOTONICS, V8, P530, DOI [10.1038/NPHOTON.2014.132, 10.1038/nphoton.2014.132]
[7]   Resolving molecular vibronic structure using high-sensitivity two-dimensional electronic spectroscopy [J].
Bizimana, Laurie A. ;
Brazard, Johanna ;
Carbery, William P. ;
Gellen, Tobias ;
Turner, Daniel B. .
JOURNAL OF CHEMICAL PHYSICS, 2015, 143 (16)
[8]   Infrared spectroscopy of size-selected water and methanol clusters [J].
Buck, U ;
Huisken, F .
CHEMICAL REVIEWS, 2000, 100 (11) :3863-3890
[9]   TUNABLE FAR INFRARED-LASER SPECTROSCOPY OF VANDERWAALS BONDS - EXTENDED MEASUREMENTS ON THE LOWEST SIGMA-BEND OF ARHCL [J].
BUSAROW, KL ;
BLAKE, GA ;
LAUGHLIN, KB ;
COHEN, RC ;
LEE, YT ;
SAYKALLY, RJ .
JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (03) :1268-1276
[10]  
Coddington I, 2016, OPTICA, V3, P414, DOI [10.1364/optica.3.000414, 10.1364/OPTICA.3.000414]
1234567