Electrochemical switching of monomer-associate in the system tetraviologen calix[4]resorcinol-3,7-di(l-menthyl)-1,5-di(p-sulfonatophenyl)-1,5-diaza-3,7-diphosphacyclooctane

被引：5

作者：

Nasybullina, G. R. ^{[1
]}

Yanilkin, V. V. ^{[1
]}

Ziganshina, A. Yu ^{[1
]}

Morozov, V. I. ^{[1
]}

Sultanova, E. D. ^{[1
]}

Korshin, D. E. ^{[1
]}

Spiridonova, Yu S. ^{[1
]}

Balueva, A. S. ^{[1
]}

Karasik, A. A. ^{[1
]}

Konovalov, A. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

calix[4]resorcinol; methyl viologen; association; pi-polymer; electrochemical control; TRANSITION-METAL-COMPLEXES; MOLECULAR RECOGNITION; REDOX; BINDING; INCLUSION; RECEPTORS; TETRATHIAFULVALENE; METHYLVIOLOGEN; RESORCINARENE; LUMINESCENCE;

D O I：

10.1007/s11172-013-0315-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The possibility of controlling the association of tetraviologen calix[4]resorcinol (MVCA-C-5 (8+)) with 3,7-di(l-menthyl)-1,5-di(p-sulfonatophenyl)-1,5-diaza-3,7-diphosphacyclooctane (APCO-2(2-)) in the electrochemical cycle of reduction-reoxidation of viologen units was shown. Reduction to tetra(radical cation) MVCA-C-5 (4+center dot) transforms monomeric MVCA-C-5 (8+) and APCO-2(2-) into the associate (pi-polymer) (xAPCO-2(2-)center dot yMVCA-C-5 (4+center dot)) (n) , which is completely returned by reoxidation to the initial state.

引用

页码：2158 / 2170

页数：13

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