(Z)-6-[(5-Chloro-2-hydroxyanilino)methylene]-4-methoxycyclohexa-2,4-dienone 0.25-hydrate

被引:0
|
作者
Ozek, Arzu [1 ]
Buyukgungor, Orhan [1 ]
Albayrak, Cigdem
Odabasoglu, Mustafa [2 ]
机构
[1] Ondokuz Mayis Univ, Dept Phys, TR-55139 Kurupelit, Turkey
[2] Pamukkale Univ, Denizli Tech Vocat Sch, Denizli, Turkey
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
D O I
10.1107/S160053680901410X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C14H12ClNO3 center dot 0.25H(2)O, exists in the keto-amine form, and the aromatic rings are oriented at a dihedral angle of 7.24 (7)degrees. Bifurcated intramolecular N-H center dot center dot center dot(O,O) hydrogen bonds result in the formation of planar six- and five-membered rings. In the crystal structure, intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link the molecules into chains. pi-pi contacts between benzene rings [centroid-centroid distance = 3.5065 (9) angstrom] may further stabilize the structure. There also exists a weak C-H center dot center dot center dot pi interaction.
引用
收藏
页码:O1104 / U2779
页数:10
相关论文
共 44 条
  • [1] 6-[(5-tert-Butyl-2-hydroxyanilino)methylene]cyclohexa-2,4-dienone
    Boehme, Uwe
    Fels, Sabine
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O14 - U2607
  • [2] Spectroscopic Studies and Crystal Structure of (Z)-6-[(2-hydroxyphenylamino)methylene]-2-methoxycyclohexa-2,4-dienone
    Hüseyin Ünver
    Mustafa Yıldız
    Aşkın Kiraz
    Özen Özgen
    Journal of Chemical Crystallography, 2009, 39 : 17 - 23
  • [3] Spectroscopic Studies and Crystal Structure of (Z)-6-[(2-hydroxyphenylamino)methylene]-2-methoxycyclohexa-2,4-dienone
    Uenver, Hueseyin
    Yildiz, Mustafa
    Kiraz, Askin
    Oezgen, Oezen
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2009, 39 (01) : 17 - 23
  • [4] (Z)-6-[(5-Chloro-2-hydroxyphenyl)aminomethylene]-2-ethoxycyclohexa-2,4-dienone
    Ozek, Arzu
    Albayrak, Cigdem
    Bueyuekguengoer, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2153 - U2024
  • [5] 3-Diethylamino-6-[(Z)-(4-hydroxyanilino)methylidene]cyclohexa-2,4-dienone
    Soydemir, Erkan
    Buyukgungor, Orhan
    Albayrak, Cigdem
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O3138 - U321
  • [6] (Z)-4-[(E)-(4-Butylphenyl)diazenyl]-6-{[1,3-dihydroxy-2-(hydroxymethyl) propan-2-ylamino]methylene}-2-methoxycyclohexa-2,4-dienone
    Ersanli, CC
    Albayrak, C
    Odabasoglu, M
    Büyükgüngör, O
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O4139 - O4141
  • [7] Structural and aromatic aspects for tautomerism of (Z)-6-((4-bromophenylamino)methylene)-2,3-dihydroxycyclohexa-2,4-dienone
    Karabiyik, Hasan
    Petek, Hande
    Iskeleli, Nazan Ocak
    Albayrak, Cigdem
    STRUCTURAL CHEMISTRY, 2009, 20 (06) : 1055 - 1065
  • [8] Structural and aromatic aspects for tautomerism of (Z)-6-((4-bromophenylamino)methylene)-2,3-dihydroxycyclohexa-2,4-dienone
    Hasan Karabıyık
    Hande Petek
    Nazan Ocak İskeleli
    Çiğdem Albayrak
    Structural Chemistry, 2009, 20 : 1055 - 1065
  • [9] Synthesis, spectroscopic characterizations and quantum chemical computational studies of (Z)-4-[(E)-p-tolyldiazenyl]-6-[(2-hydroxyphenylamino)methylene]-2-methoxycyclohexa-2,4-dienone
    Odabasoglu, Mustafa
    Albayrak, Cigdem
    Kosar, Basak
    Buyukgungor, Orhan
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 92 : 357 - 364
  • [10] Crystal structures of 6-[(2-hydroxy-1,1-bis-hydroxymethyl-ethylamino)-methylene]-4-nitro-cyclohexa-2,4-dienone hydrate and 6-[(2-hydroxy-1,1-bis-hydroxymethyl-ethylamino)-methylene]-4-bromo-cyclohexa-2,4-dienone
    Chumakov, Yu. M.
    Tzapkov, V. I.
    Bocelli, G.
    Antosyak, B. Ya.
    Gulya, A. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 47 (02) : 346 - 351