Effective removal of methylene blue and orange II by subsequent immobilized laccase decolorization on crosslinked polymethacrylate/carbon nanotubes

被引:19
作者
Lai, Yuxian [1 ]
Wang, Fei [2 ]
Zhang, Yimei [1 ,2 ]
Ou, Ping [3 ]
Wu, Panpan [1 ]
Fang, Qinglu [1 ]
Li, Shuai [2 ]
Chen, Zhuang [2 ]
机构
[1] North China Elect Power Univ, Coll Environm Sci & Engn, Beijing 102206, Peoples R China
[2] North China Elect Power Univ, Suzhou Res Acad, Lab Environm Remediat & Funct Mat, Suzhou 215213, Peoples R China
[3] Suzhou Univ Sci & Technol, Suzhou 215009, Peoples R China
基金
中国国家自然科学基金;
关键词
methylene blue; orange II; crosslinked; immobilized laccase; carbon nanotubes; CARBON NANOTUBES; TRAMETES-VERSICOLOR; IRON NANOPARTICLES; DEGRADATION; DYES; NANOCOMPOSITE; CHITOSAN; BIODEGRADATION; POLYMERIZATION; DETOXIFICATION;
D O I
10.1088/2053-1591/ab26a5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this research, methylene blue (MB) and orange II (OII) were effectively removed through subsequent immobilized laccase degradation on crosslinked polymethacrylate (PMMA)/carbon nanotubes (CNTs). PMMA was coated on CNTs by microemulsion polymerization, and then laccase was immobilized on the PMMA-CNTs. Laccase immobilized on PMMA-CNTs shows a high catalytic ability and stable reusability. The immobilized laccase exhibits a high specific laccase activity and a high decolorization rate on the azo dyes, which the maximum decolorization rate for MB can reach 96% and maximum decolorization rate for OH is 74%. Additionally, the decolorization rate was decreased only about 10% after 10 successive cycles. The immobilized laccase can be a promising multifunction material in wastewater treatment, which would be applied in the decolorization of azo dyes.
引用
收藏
页数:10
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