Novel imidazolium-embedded and imidazolium-spaced octadecyl stationary phases for reversed phase liquid chromatography

被引：46

作者：

Zhang, Mingliang ^{[1
,2
,3
]}

Chen, Jia ^{[1
,2
]}

Gu, Tongnian ^{[1
,2
]}

Qiu, Hongdeng ^{[1
,2
]}

Jiang, Shengxiang ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China

[3] Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

TALANTA | 2014年 / 126卷

基金：

中国国家自然科学基金;

关键词：

Polar-embedded; Polar-spaced; Surface-confined ionic liquid; Reversed-phase liquid chromatography; Linear solvation energy relationships; SOLVATION ENERGY RELATIONSHIPS; CONFINED IONIC-LIQUID; RETENTION CHARACTERISTICS; RP-HPLC; SOLVENT PROPERTIES; ANION-EXCHANGE; SOLID-PHASE; SELECTIVITY; PERFORMANCE; SILICA;

D O I：

10.1016/j.talanta.2014.03.057

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Two new stationary phases modified by alkylimidazoliums were prepared for the first time and characterized. One of the new phases was obtained via monomeric immobilization of octadecylimidazole to gamma-chloropropyltrimethoxysilane modified silica to form polar-embedded phase; the other one was prepared by co-immobilization of two silane coupling agents (gamma-chloropropyltrichlorosilane and octadecyltrichlorosilane) to silica, followed by quaternization of methylimidazole to form polar-spaced phase. This study was intended to compare the retention characteristics of these two stationary phases using linear solvation energy relationships model, as well as to examine the difference in selectivity by eluting alkylbenzenes, alkylnaphthalenes, condensed-ring and phenylene polynuclear aromatic hydrocarbons on both phases. Different effects of distributions of polar functional group and octadecyl chain were found to impact the chromatographic properties. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：177 / 184

页数：8

共 50 条

[1] Determination of sets of solute descriptors from chromatographic measurements
Abraham, MH
Ibrahim, A
Zissimos, AM
[J]. JOURNAL OF CHROMATOGRAPHY A, 2004, 1037 (1-2) : 29 - 47
[2] Abraham MH, 1997, J PHYS ORG CHEM, V10, P358, DOI 10.1002/(SICI)1099-1395(199705)10:5<358::AID-POC907>3.0.CO
[3] 2-N
[4] THERMODYNAMICS OF SOLUTE TRANSFER FROM WATER TO HEXADECANE
ABRAHAM, MH
WHITING, GS
FUCHS, R
CHAMBERS, EJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (02): : 291 - 300
[5] Comparison of Different Silica-Based Imidazolium Stationary Phases for LC in Separation of Alkaloids
Bi, Wentao
Row, Kyung Ho
[J]. CHROMATOGRAPHIA, 2010, 71 (1-2) : 25 - 30
[6] Characterization of new N,O-dialkyl phosphoramidate-bonded stationary phases for reversed-phase HPLC - retention and selectivity
Bocian, Szymon
Paca, Magdalena
Buszewski, Boguslaw
[J]. ANALYST, 2013, 138 (18) : 5221 - 5229
[7] New alkyl-phosphate bonded stationary phases for liquid chromatographic separation of biologically active compounds
Bocian, Szymon
Nowaczyk, Alicja
Buszewski, Boguslaw
[J]. ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2012, 404 (03) : 731 - 740
[8] Effect of water, methanol, and acetonitrile on solvent relaxation and rotational relaxation of coumarin 153 in neat 1-hexyl-3-methylimidazolium hexafluorophosphate
Chakrabarty, D
Chakraborty, A
Seth, D
Sarkar, N
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (09) : 1764 - 1769
[9] Comparison of retention on traditional alkyl, polar endcapped, and polar embedded group stationary phases
Coym, Jason W.
[J]. JOURNAL OF SEPARATION SCIENCE, 2008, 31 (10) : 1712 - 1718
[10] Application of a modified linear solvation energy relationship (LSER) model to retention on a butylimidazolium-based column for high performance liquid chromatography
Fields, P. R.
Sun, Y.
Stalcup, A. M.
[J]. JOURNAL OF CHROMATOGRAPHY A, 2011, 1218 (03) : 467 - 475

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