Modification of coordination networks through a photoinduced charge transfer process

被引：27

作者：

Easun, Timothy L. ^{[1
]}

Jia, Junhua ^{[1
]}

Reade, Thomas J. ^{[1
]}

Sun, Xue-Zhong ^{[1
]}

Davies, E. Stephen ^{[1
]}

Blake, Alexander J. ^{[1
]}

George, Michael W. ^{[1
]}

Champness, Neil R. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL SCIENCE | 2014年 / 5卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; PHOTOCRYSTALLOGRAPHIC IDENTIFICATION; ENERGY-TRANSFER; CRYSTAL; PHOTOCATALYSIS; TERMINOLOGY; CHEMISTRY; POLYMERS; MOFS;

D O I：

10.1039/c3sc52745j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-bearing coordination network synthesised from Re(2,20-bipyridine-5,50-dicarboxylate)(CO)(3)Cl bridging ligands and Cu(II) nodes, [{Cu(DMF)(H2O)[ LRe(CO)(3)Cl]}center dot DMF]infinity ReCu, undergoes an irreversible photoinduced charge transfer process. We demonstrate using time-resolved IR spectroscopy the nature of this photoinduced process and how, under suitable conditions, it is possible to initiate irreversible modification of the crystal through induction of the charge transfer process. As a result we are able to use the photoinduced process, which arises purely as a result of the structure of the coordination network, to write on crystals.

引用

页码：539 / 544

页数：6

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