Gold-Catalyzed 6-Exo-Dig Cycloisomerization: A Versatile Approach to Functionalized Phenanthrenes

被引：31

作者：

Shu, Chao ^{[1
,2
]}

Li, Long ^{[1
,2
]}

Chen, Cheng-Bin ^{[1
,2
]}

Shen, Hong-Cheng ^{[1
,2
]}

Ye, Long-Wu ^{[1
,2
]}

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Key Lab Chem Biol Fujian Prov, Xiamen 361005, Fujian, Peoples R China

[2] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Fujian, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2014年 / 9卷 / 06期

基金：

中国国家自然科学基金;

关键词：

cycloisomerization; gold; homogeneous catalysis; hydroarylation; phenanthrenes; POLYCYCLIC AROMATIC-HYDROCARBONS; ONE-POT SYNTHESIS; HYDROARYLATION REACTIONS; PHOTOPHYSICAL PROPERTIES; OXIDATIVE CYCLIZATION; CARBENE COMPLEXES; ALKYNES; CRYPTOPLEURINE; CONSTRUCTION; (-)-ANTOFINE;

D O I：

10.1002/asia.201400034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel gold-catalyzed 6-exo-dig cycloisomerization of o-propargylbiaryls has been developed that provides ready access to functionalized phenanthrenes in largely good to excellent yields. Notable features of this method are readily available starting materials, mild reaction conditions, and broad substrate scope.

引用

页码：1525 / 1529

页数：5

共 91 条

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