Synthesis and spectroscopic studies of iron (III) complex with a quinolone family member (pipemidic acid)

被引：28

作者：

Skrzypek, D.

Szymanska, B.

Kovala-Demertzi, Dimitra

Wiecek, Joanna

Talik, E.

Demertzis, Mavroudis A.

机构：

[1] Silesian Univ, A Chelkowski Inst Phys, PL-40007 Katowice, Poland

[2] Univ Ioannina, Sect Inorgan & Analyt Chem, Dept Chem, Ioannina 45110, Greece

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2006年 / 67卷 / 12期

关键词：

non-crystalline materials; chemical synthesis; EPR;

D O I：

10.1016/j.jpcs.2006.07.013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interaction of iron (111) with pipemidic acid, Hpipem, afforded the complex [Fe (pipem) (HO)(2) (H2O)](2). The new complex has been characterised by elemental analyses, infra-red, EPR and XPS spectroscopies. The monoanion, pipem, exhibits O, O ligation through the carbonyl and carboxylato oxygen atoms. Six coordinate dimer distorted octahedral configuration has been proposed for [Fe (pipem) (HO)(2) (H2O)](2). (c) 2006 Elsevier Ltd. All rights reserved.

引用

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页码：2550 / 2558

页数：9

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