Properties of high yield synthesised carbon nano fibres/Portland cement composite

被引:19
作者
Cwirzen, A. [1 ]
Habermehl-Cwirzen, K. [1 ]
Shandakov, D. [2 ,3 ]
Nasibulina, L. I. [2 ,3 ]
Nasibulin, A. G. [2 ,3 ]
Mudimela, P. R. [2 ,3 ]
Kauppinen, E. I. [2 ,3 ]
Penttala, V. [1 ]
机构
[1] Aalto Univ, Lab Bldg Mat Technol, Fac Engn & Architecture, FIN-02150 Espoo, Finland
[2] Aalto Univ, Phys Lab, FIN-02150 Espoo, Finland
[3] Aalto Univ, Ctr New Mat, FIN-02150 Espoo, Finland
关键词
NANOTUBES; DECORATION;
D O I
10.1680/adcr.8.00021
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The compressive strength and electrical resistivity of hardened pastes produced either from nanomodified Portland sulfate-resistant cement (CHH) or a mixture of nanomodified and pristine sulfate-resistant cements Were determined. The nanomodification included grow carbon nanotubes (CNTs) and carbon nanofibres (CNFs) on the cement particles. Pastes having a water-to-binder ratio of 0.5 were produced. The test results revealed that partial replacement of sulfate-resistant cement by CHH cement decreased the electrical resistivity of the 28 day old specimens hat worsened the mechanical properties. The lower compressive strength was attributed to a lower, degree of hydration of the CHH cement. The addition of a mixture of surfactants enabled the production of specimens consisting entirely of CHH cement. The hardened material obtained was characterised by a nearly doubled compressive strength in comparison with the reference specimens made from pristine sulfate-resistant cement. This was attributed to a high degree of hydration as well as reinforcing action of the CNTs and CNFs The electrical resistivity was lowered by one order of magnitude classifying this material as a semiconductor.
引用
收藏
页码:141 / 146
页数:6
相关论文
共 19 条
[1]   Surface decoration of carbon nanotubes and mechanical properties of cement/carbon nanotube composites [J].
Cwirzen, A. ;
Habermehl-Cwirzen, K. ;
Penttala, V. .
ADVANCES IN CEMENT RESEARCH, 2008, 20 (02) :65-73
[2]  
DE LARRARD F, 1989, CEMENT CONCRETE RES, V19, P161
[3]  
Dubois P, 2006, ADV ENG MATER, V8, P147, DOI 10.1002/adem.200500256
[4]   Decoration of carbon nanotubes [J].
Ebbesen, TW ;
Hiura, H ;
Bisher, ME ;
Treacy, MMJ ;
ShreeveKeyer, JL ;
Haushalter, RC .
ADVANCED MATERIALS, 1996, 8 (02) :155-&
[5]   Carbon nanotube-ceramic composites [J].
Gao, Lian ;
Jiang, Linqin ;
Sun, Jing .
JOURNAL OF ELECTROCERAMICS, 2006, 17 (01) :51-55
[6]   Carbon nanotubes, buckyballs, ropes, and a universal graphitic potential [J].
Girifalco, LA ;
Hodak, M ;
Lee, RS .
PHYSICAL REVIEW B, 2000, 62 (19) :13104-13110
[7]   In situ chemical experiments in carbon nanotubes [J].
Gogotsi, Y ;
Naguib, N ;
Libera, JA .
CHEMICAL PHYSICS LETTERS, 2002, 365 (3-4) :354-360
[8]   An examination of fly ash carbon and its interactions with air entraining agent [J].
Hill, RL ;
Sarkar, SL ;
Rathbone, RF ;
Hower, JC .
CEMENT AND CONCRETE RESEARCH, 1997, 27 (02) :193-204
[9]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[10]  
KOWLAD T, 2004, P INT S ULTR PERF CO, P195