In Situ Fabrication of Foamed Titania Carbon Nitride Nanocomposite and Its Synergetic Visible-Light Photocatalytic Performance

被引:20
作者
Shakeel, Muhammad [1 ]
Li, Baoshan [1 ]
Yasin, Ghulam [1 ]
Arif, Muhammad [1 ]
Rehman, Wajid [2 ]
Khan, Hashmat Daud [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Hazara Univ, Dept Chem, Mansehra 21120, Khyber Pakhtunk, Pakistan
基金
中国国家自然科学基金;
关键词
COMPOSITE; DEGRADATION; NANOSHEETS; CATALYST; G-C3N4; ELECTROCATALYST; SEMICONDUCTORS; SPHERES; GROWTH; ARRAYS;
D O I
10.1021/acs.iecr.8b01090
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Efficient visible-light-driven materials are key for environmental remediation. The foamed titania-carbon nitride nanocomposite (FTCN) was synthesized by in situ microemulsification followed by calcination using bulk g-C3N4 and TBOT. During calcination the bulk g-C3N4 transformed into ultrathin nanosheets. The nanocomposite is characterize by state of the art physicochemical techniques; the structure look like foam with mesoporous cavities. The carbon nitride nanosheets were uniformly distributed and mostly embedded inside the bulk of titania with close interfacial connection. The FTCN-3 nanocomposite has superior degradation performance for MB and RhB with rate constants of 0.096 and 0.061 (min(-1)), respectively. This upmost photocatalytic activity could be ascribed to large S-BET (339 m(2) g(-1)) and foamed structure. These are considered significant factors for efficient visible-light absorption and slow recombination of charges during photocatalysis. This is an inventive strategy to enhance the potential of TiO2 in diverse fields.
引用
收藏
页码:8152 / 8159
页数:8
相关论文
共 57 条
  • [1] Comparative performance of M-MCM-41 (M: Cu, Co, Ni, Pd, Zn and Sn) catalysts for steam reforming of methanol
    Abrokwah, Richard Y.
    Deshmane, Vishwanath G.
    Kuila, Debasish
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 425 : 10 - 20
  • [2] Polymeric Photocatalysts Based on Graphitic Carbon Nitride
    Cao, Shaowen
    Low, Jingxiang
    Yu, Jiaguo
    Jaroniec, Mietek
    [J]. ADVANCED MATERIALS, 2015, 27 (13) : 2150 - 2176
  • [3] g-C3N4-Based Photocatalysts for Hydrogen Generation
    Cao, Shaowen
    Yu, Jiaguo
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (12): : 2101 - 2107
  • [4] Fabrication, characterization, and photocatalytic performance of exfoliated g-C3N4-TiO2 hybrids
    Chang, Fei
    Zhang, Jian
    Xie, Yunchao
    Chen, Juan
    Li, Chenlu
    Wang, Jie
    Luo, Jieru
    Deng, Baoqing
    Hu, Xuefeng
    [J]. APPLIED SURFACE SCIENCE, 2014, 311 : 574 - 581
  • [5] Growth of g-C3N4 on mesoporous TiO2 spheres with high photocatalytic activity under visible light irradiation
    Chen, Xiaofang
    Wei, Jing
    Hou, Rujing
    Liang, Yan
    Xie, Zongli
    Zhu, Yonggang
    Zhang, Xiwang
    Wang, Huanting
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 188 : 342 - 350
  • [6] A review on non metal ion doped titania for the photocatalytic degradation of organic pollutants under UV/solar light: Role of photogenerated charge carrier dynamics in enhancing the activity
    Devi, L. Gomathi
    Kavitha, R.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 140 : 559 - 587
  • [7] Spherical silica micro/nanomaterials with hierarchical structures: Synthesis and applications
    Du, Xin
    He, Junhui
    [J]. NANOSCALE, 2011, 3 (10) : 3984 - 4002
  • [8] BiOBr-carbon nitride heterojunctions: synthesis, enhanced activity and photocatalytic mechanism
    Fu, Jie
    Tian, Yanlong
    Chang, Binbin
    Xi, Fengna
    Dong, Xiaoping
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (39) : 21159 - 21166
  • [9] Novel visible light-induced g-C3N4/Bi2WO6 composite photocatalysts for efficient degradation of methyl orange
    Ge, Lei
    Han, Changcun
    Liu, Jing
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 108 (1-2) : 100 - 107
  • [10] An Advanced Ni-Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation
    Gong, Ming
    Li, Yanguang
    Wang, Hailiang
    Liang, Yongye
    Wu, Justin Z.
    Zhou, Jigang
    Wang, Jian
    Regier, Tom
    Wei, Fei
    Dai, Hongjie
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (23) : 8452 - 8455