The N,N′-bis(trimethylsilyl)pentafluorobenzamidinate ligand:: enhanced ethene oligomerisation with a neutral V(III) bis(benzamidinate) alkyl catalyst

被引：66

作者：

Brussee, EAC ^{[1
]}

Meetsma, A ^{[1
]}

Hessen, B ^{[1
]}

Teuben, JH ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst Chem & Chem Engn, Ctr Catalyt Olefin Polymerisat, NL-9747 AG Groningen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 06期

关键词：

D O I：

10.1039/b000397m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pentafluorobenzamidinate ligand [C6F5C(NSiMe3)(2)](-) is reported, together with its bis(benzamidinate) vanadium(iii) methyl derivative; the latter is considerably more active in catalytic ethene oligomerisation than its non-fluorinated analogue.

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收藏

页码：497 / 498

页数：2

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