Fabrication of Micropatterned Stimulus-Responsive Polymer-Brush 'Anemone'

被引:32
作者
Chen, Tao [1 ,2 ]
Zhong, Jianming [1 ,2 ]
Chang, Debby P. [1 ,2 ]
Carcia, Andres [1 ,2 ]
Zauscher, Stefan [1 ,2 ]
机构
[1] Duke Univ, Dept Mech Engn & Mat Sci, Durham, NC 27708 USA
[2] Duke Univ, Ctr Biolo Inspired Mat & Mat Syst, Durham, NC 27708 USA
基金
美国国家科学基金会;
关键词
SELF-ASSEMBLED MONOLAYERS; SURFACE-INITIATED POLYMERIZATION; SCALE PHASE-SEPARATION; MICROFLUIDIC CHANNELS; CHEMICAL LITHOGRAPHY; GOLD; NANOPATTERNS; AU(111); CHAIN; COADSORPTION;
D O I
10.1002/adma.200802484
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple strategy to fabricate stimulus-responsive patterned PNIPAAM-brush microstructures ('anemones') is presented. The size of the microstructures can be adjusted by setting the composition of thiol and the contact pressure. We demonstrate that the patterned PNIPAAM-brush microstructures have a triggerable and reversible conformation transition, and can potentially be used as microcontainers to reversibly dock and release microparticles.
引用
收藏
页码:1825 / +
页数:6
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