Adsorption of Cr(VI) onto Activated Carbons Prepared from Indigenous Materials

被引:8
|
作者
Karthikeyan, G. [1 ]
Ilango, S. Siva [1 ]
机构
[1] Gandhigram Rural Univ, Dept Chem, Gandhigram 624302, Tamil Nadu, India
关键词
Adsorption; Activated carbons; Adsorption Isotherms; Chi-square analysis; Intraparticle diffusion;
D O I
10.1155/2008/109398
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The adsorption of chromium(VI) on activated carbons prepared from low cost materials has been studied by batch process. The influences of various parameters like contact time, dosage, pH, pHzpc and co-ions were experimentally verified. The adsorption of Cr(VI) is maximum at strongly acidic medium (pH 3). Adsorption is explained using Langmuir and Freundlich isotherms with help of chi-square analysis. Thermodynamic parameters like Delta G(0), Delta H-0 and Delta S-0 were calculated to understand the nature of adsorption. The surface morphology of the three activated carbons before and after metal sorption was verified using scanning electron microscope (SEM) and X-ray diffraction studies (XRD).
引用
收藏
页码:666 / 678
页数:13
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