Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents

被引：8

作者：

Uscumlic, Gordana S. ^{[1
]}

Zreigh, Mohamed M. ^{[1
]}

Mijin, Dusan Z. ^{[1
]}

机构：

[1] Univ Belgrade, Dept Organ Chem, Fac Technol & Met, Belgrade 11120, Serbia

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2006年 / 71卷 / 05期

关键词：

isocyanurates; binder; bonding agent; interactions; composite material; hydrogen bonding; FTIR;

D O I：

10.2298/JSC0605445U

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH, CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature, isolation techniques, as well as purification and identification of the products. All the synthesized isocyanurates were identified by their melting point and FTIR, H-1 NMR and UV spectroscopic data. Fourier transform infrared spectrophotometry was also used to study the interaction between ammonium perchlorate, hydroxyl terminated poly(butadiene), carboxyl terminated poly(butadiene), poly(butadiene-co-acrylonitrile), poly(propylene ether), cyclotrimethylenetrinitramine and the compounds synthesized in this work, which can serve as bonding agents. The results show that tris(2-hydroxyethyl)isocyanurate is a universal bonding agent for the ammonium perchlorate/carboxyl terminated poly(butadiene)/cyclotrimethylenetrinitramine composite propellant system.

引用

页码：445 / 458

页数：14