共 64 条
Facile synthesis of platinum-ruthenium nanodendrites supported on reduced graphene oxide with enhanced electrocatalytic properties
被引:34
作者:
Zheng, Jie-Ning
[1
]
Li, Shan-Shan
[1
]
Chen, Fang-Yi
[1
]
Bao, Ning
[2
]
Wang, Ai-Jun
[1
]
Chen, Jian-Rong
[1
]
Feng, Jiu-Ju
[1
]
机构:
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Coll Geog & Environm Sci, Jinhua 321004, Peoples R China
[2] Nantong Univ, Sch Publ Hlth, Nantong 226019, Peoples R China
关键词:
Platinum-ruthenium nanodendrites;
Reduced grapherie oxide;
Hexadecylpyridinium chloride;
Catalytic activity;
Ethylene glycol;
ORDERED MESOPOROUS CARBON;
OXYGEN REDUCTION REACTION;
METHANOL FUEL-CELLS;
ETHYLENE-GLYCOL;
FORMIC-ACID;
CATALYTIC PERFORMANCE;
ALLOY NANOPARTICLES;
ELECTROOXIDATION;
OXIDATION;
NANOCRYSTALS;
D O I:
10.1016/j.jpowsour.2014.04.128
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
In this report, a simple and facile solvothermal method is developed for fabrication of platinum ruthenium (PtRu) nanodendrites supported on reduced graphene oxide (PtRu-RGO) in the ethylene glycol (EG) system, using hexadecylpyridinium chloride (HDPC) as a shape-directing agent. The as-prepared nanocomposites show the superior catalytic activity and better stability towards EG oxidation, compared with RGO-supported Pt nanoparticles and commercial PtRu/C (Pt 30 wt. %, Ru 15 wt. %) catalysts. This strategy may open a new route to design and prepare advanced electrocatalysts in direct EG fuel cells. (C) 2014 Elsevier B.V. All rights reserved.
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页码:259 / 267
页数:9
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