Facile synthesis of platinum-ruthenium nanodendrites supported on reduced graphene oxide with enhanced electrocatalytic properties

被引:34
作者
Zheng, Jie-Ning [1 ]
Li, Shan-Shan [1 ]
Chen, Fang-Yi [1 ]
Bao, Ning [2 ]
Wang, Ai-Jun [1 ]
Chen, Jian-Rong [1 ]
Feng, Jiu-Ju [1 ]
机构
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Coll Geog & Environm Sci, Jinhua 321004, Peoples R China
[2] Nantong Univ, Sch Publ Hlth, Nantong 226019, Peoples R China
关键词
Platinum-ruthenium nanodendrites; Reduced grapherie oxide; Hexadecylpyridinium chloride; Catalytic activity; Ethylene glycol; ORDERED MESOPOROUS CARBON; OXYGEN REDUCTION REACTION; METHANOL FUEL-CELLS; ETHYLENE-GLYCOL; FORMIC-ACID; CATALYTIC PERFORMANCE; ALLOY NANOPARTICLES; ELECTROOXIDATION; OXIDATION; NANOCRYSTALS;
D O I
10.1016/j.jpowsour.2014.04.128
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this report, a simple and facile solvothermal method is developed for fabrication of platinum ruthenium (PtRu) nanodendrites supported on reduced graphene oxide (PtRu-RGO) in the ethylene glycol (EG) system, using hexadecylpyridinium chloride (HDPC) as a shape-directing agent. The as-prepared nanocomposites show the superior catalytic activity and better stability towards EG oxidation, compared with RGO-supported Pt nanoparticles and commercial PtRu/C (Pt 30 wt. %, Ru 15 wt. %) catalysts. This strategy may open a new route to design and prepare advanced electrocatalysts in direct EG fuel cells. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:259 / 267
页数:9
相关论文
共 64 条
[41]   Highly dispersed ultrafine Pt and PtRu nanoparticles on graphene: formation mechanism and electrocatalytic activity [J].
Nethravathi, C. ;
Anumol, E. A. ;
Rajamathi, M. ;
Ravishankar, N. .
NANOSCALE, 2011, 3 (02) :569-571
[42]   Imperfect oriented attachment: Dislocation generation in defect-free nanocrystals [J].
Penn, RL ;
Banfield, JF .
SCIENCE, 1998, 281 (5379) :969-971
[43]   Studying disorder in graphite-based systems by Raman spectroscopy [J].
Pimenta, M. A. ;
Dresselhaus, G. ;
Dresselhaus, M. S. ;
Cancado, L. G. ;
Jorio, A. ;
Saito, R. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (11) :1276-1291
[44]   Tailoring a Pt-Ru catalyst for enhanced methanol electro-oxidation [J].
Raman, R. K. ;
Shukla, A. K. ;
Gayen, A. ;
Hegde, M. S. ;
Priolkar, K. R. ;
Sarode, P. R. ;
Emura, S. .
JOURNAL OF POWER SOURCES, 2006, 157 (01) :45-55
[45]   Graphene-Supported Pt-Au Alloy Nanoparticles: A Highly Efficient Anode for Direct Formic Acid Fuel Cells [J].
Rao, Chitturi Venkateswara ;
Cabrera, Carlos R. ;
Ishikawa, Yasuyuki .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (44) :21963-21970
[46]   Pt and Pt-Ru nanoparticles decorated polypyrrole/multiwalled carbon nanotubes and their catalytic activity towards methanol oxidation [J].
Selvaraj, Vaithilingam ;
Alagar, Muthukaruppan .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (05) :1145-1153
[47]   Rapid Microwave Synthesis of CO Tolerant Reduced Graphene Oxide-Supported Platinum Electrocatalysts for Oxidation of Methanol [J].
Sharma, Surbhi ;
Ganguly, Abhijit ;
Papakonstantinou, Pagona ;
Miao, Xiaopei ;
Li, Meixian ;
Hutchison, John L. ;
Delichatsios, Michael ;
Ukleja, Sebastian .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (45) :19459-19466
[48]   Nanostructured Pt and Pt-Sn catalysts supported on oxidized carbon nanotubes for ethanol and ethylene glycol electro-oxidation [J].
Sieben, J. M. ;
Duarte, M. M. E. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (05) :3313-3321
[49]   Novel Pt-Ru nanoparticles formed by vapour deposition as efficient electrocatalyst for methanol oxidation - Part II. Electrocatalytic activity [J].
Sivakumar, P ;
Tricoli, V .
ELECTROCHIMICA ACTA, 2006, 51 (07) :1235-1243
[50]   Synthesis and applications of graphene-based noble metal nanostructures [J].
Tan, Chaoliang ;
Huang, Xiao ;
Zhang, Hua .
MATERIALS TODAY, 2013, 16 (1-2) :29-36