Facile synthesis of platinum-ruthenium nanodendrites supported on reduced graphene oxide with enhanced electrocatalytic properties

被引:34
作者
Zheng, Jie-Ning [1 ]
Li, Shan-Shan [1 ]
Chen, Fang-Yi [1 ]
Bao, Ning [2 ]
Wang, Ai-Jun [1 ]
Chen, Jian-Rong [1 ]
Feng, Jiu-Ju [1 ]
机构
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Coll Geog & Environm Sci, Jinhua 321004, Peoples R China
[2] Nantong Univ, Sch Publ Hlth, Nantong 226019, Peoples R China
关键词
Platinum-ruthenium nanodendrites; Reduced grapherie oxide; Hexadecylpyridinium chloride; Catalytic activity; Ethylene glycol; ORDERED MESOPOROUS CARBON; OXYGEN REDUCTION REACTION; METHANOL FUEL-CELLS; ETHYLENE-GLYCOL; FORMIC-ACID; CATALYTIC PERFORMANCE; ALLOY NANOPARTICLES; ELECTROOXIDATION; OXIDATION; NANOCRYSTALS;
D O I
10.1016/j.jpowsour.2014.04.128
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this report, a simple and facile solvothermal method is developed for fabrication of platinum ruthenium (PtRu) nanodendrites supported on reduced graphene oxide (PtRu-RGO) in the ethylene glycol (EG) system, using hexadecylpyridinium chloride (HDPC) as a shape-directing agent. The as-prepared nanocomposites show the superior catalytic activity and better stability towards EG oxidation, compared with RGO-supported Pt nanoparticles and commercial PtRu/C (Pt 30 wt. %, Ru 15 wt. %) catalysts. This strategy may open a new route to design and prepare advanced electrocatalysts in direct EG fuel cells. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:259 / 267
页数:9
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