Isothermal diagrams of the Li2O-MnO-MnO2 system

被引：10

作者：

Buzanov, G. A. ^{[1
]}

Nipan, G. D. ^{[1
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

DOKLADY CHEMISTRY | 2015年 / 465卷

关键词：

MANGANESE OXIDES; SPINEL; STABILITY; LIMN2O4; MN;

D O I：

10.1134/S0012500815110063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isothermal diagrams of the Li2O-MnO-MnO2 system at an oxygen pressure up to 100 kPa were constructed, which allow to consistently represent phase transformations involving stable ternary phases: low-temperature spinel, cubic spinel c-LiMn2O4, tetragonal phase t-LiMn2O4, orthorhombic phase LiMnO2, monoclinic solid solution Li (x) MnO2 (0.33 a parts per thousand currency sign x < 0.5), spinel-structure solid solution Li (x) Mn3-x O-4, and solid solution Mn(Li)O.

引用

页码：268 / 271

页数：4

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