Efficient catalytic wet peroxide oxidation of phenol over Fe-ZSM-5 catalyst in a fixed bed reactor

被引：83

作者：

Yan, Ying ^{[1
]}

Jiang, Songshan ^{[1
]}

Zhang, Huiping ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

SEPARATION AND PURIFICATION TECHNOLOGY | 2014年 / 133卷

基金：

中国国家自然科学基金;

关键词：

Phenol; Catalytic wet peroxide oxidation; Fe-ZSM-5; catalyst; Fixed bed reactor; HYDROGEN-PEROXIDE; WASTE-WATER; DEGRADATION; REMOVAL; COPPER; IRON; BEHAVIOR; SILICA; CARBON;

D O I：

10.1016/j.seppur.2014.07.014

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Fe-ZSM-5 catalyst was prepared for catalytic wet peroxide oxidation (CWPO) of phenol in a fixed bed reactor. The catalyst was prepared by incipient wetness impregnation and characterized by using N-2 adsorption-desorption and X-ray diffraction (XRD). The optimum operation conditions for catalytic wet peroxide oxidation of phenol over Fe-ZSM-5 catalyst were determined by investigating the effects of feed flow rate and catalyst bed height on the conversion of phenol, H2O2 and total organic carbon (TOC). In addition, stability and reusability of the Fe-ZSM-5 catalyst was studied by measuring the iron concentration leached out from the catalyst. Finally, the probable reaction mechanism of phenol oxidation over Fe-ZSM-5 catalyst in the fixed bed reactor was considered by analyzing the HPLC patterns. The experimental results showed that the Fe-ZSM-5 catalyst achieved the highest activity (99.2% phenol conversion and 77.7% TOC conversion, respectively) with remarkable low iron leaching concentration closed to zero at the temperature of 80 degrees C, feed flow rate of 2 mL/min and catalyst bed height of 3.8 cm. The Fe-ZSM-5 catalyst showed a perfect stability with low iron leaching concentration (about 1.0 mg/L) and high phenol conversion (above 95.0%) after three successive runs. Meanwhile, few intermediate products with low concentration were observed by the analysis of HPLC patterns for the CWPO of phenol in the fixed bed reactor. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：365 / 374

页数：10

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