Tungsten carbide@graphene nanoflakes: Preparation, characterization and electrochemical activity for capacitive deionization technology

被引:21
作者
Al-Enizi, Abdullah M. [1 ]
Hameed, R. M. Abdel [2 ]
El-Halwany, M. M. [3 ]
Bakrey, Mahmoud [4 ]
Shaikh, Shoyebmohamad F. [1 ]
Yousef, Ayman [5 ,6 ]
机构
[1] King Saud Univ, Dept Chem, Coll Sci, Riyadh 11451, Saudi Arabia
[2] Cairo Univ, Fac Sci, Chem Dept, Giza, Egypt
[3] Mansoura Univ, Engn Math & Phys Dept, Fac Engn, Mansoura, Egypt
[4] Aswan Univ, Fac Energy Engn, Dept Engn Mat & Design, Aswan 81528, Egypt
[5] Jazan Univ, Dept Chem Engn, Jazan 45142, Saudi Arabia
[6] Helwan Univ, Fac Engn Mataria, Dept Math & Phys Engn, Cairo 11718, Egypt
关键词
Graphene nanoflakes; Metal carbides; Capacitive deionization; Charge-discharge study; Salt removal efficiency; EFFECTIVE ELECTRODE MATERIAL; HIGH-PERFORMANCE ELECTRODES; ACTIVATED CARBON; WATER DESALINATION; 3D GRAPHENE; THIN-FILMS; COMPOSITE; OXIDE; NANOPARTICLES; DESIGN;
D O I
10.1016/j.jcis.2020.06.089
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this present work, tungsten carbide (WC) nanoparticles were intercalated between graphene nanoflakes (GNFs) using sonication followed by hydrothermal treatment. Pristine WC, GNFs and a series of WC@GNFs nanomaterials were physically characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) and water contact angle measurements. Cyclic voltammetry and electrochemical impedance studies were operated to investigate the electrochemical performance of these nanocomposites as efficient capacitive deionization (CDI) electrodes with improved electrochemical characteristics and specific capacitances in NaCl solution. Among the synthesized nanomaterials, WC@GNFs containing 10% WC displayed appreciable specific capacitance [580.00 F g(-1)], salt removal efficiency [95.50%], electrosorptive capacity [22.155 mg g(-1)] and charge efficiency [0.356] values. Accordingly, the measured results in this study indicate that WC@GNFs nanomaterials are suitable electrodes with an easy preparation route for efficient CDI technology. (C) 2020 Elsevier Inc. All rights reserved.
引用
收藏
页码:112 / 125
页数:14
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