New analysis of the ν2 band line intensities of the water molecule

被引：0

作者：

Sulakshina, ON ^{[1
]}

Borkov, YG ^{[1
]}

机构：

[1] SB RAS, Inst Atmospher Opt, Tomsk, Russia

来源：

13TH SYMPOSIUM AND SCHOOL ON HIGH-RESOLUTION MOLECULAR SPECTROSCOPY | 2000年 / 4063卷

关键词：

line intensity; effective operators; Hamiltonian; transition moment; water molecule;

D O I：

10.1117/12.375360

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

New analysis is performed of a body of data on nu(2) band line intensities of the water molecule involving mainly the transitions reported by R.A. Toth(1). As a theoretical approach the formalism of the effective-dipole moment operators is used. We have been able to determine eight effective-dipole moment parameters, which result in a satisfactory agreement between observed and calculated intensities. The total RMS deviation of the fit is 6%.

引用

页码：105 / 109

页数：5

共 7 条

[1]

[Anonymous], MOL SPECTROSCOPY MOD

[2]

Camy-Peyret C, 1975, THESIS U P M CURIE P

[3] LINE POSITIONS AND INTENSITIES IN NU2 BAND OF H2O-16 [J].