Epoxy thermosets and materials derived from bio-based monomeric phenols: Transformations and performances

被引：147
作者：
Wan, Jintao [1 ,2 ]
Zhao, Jianqing [3 ]
Zhang, Xianwei [4 ]
Fan, Hong [4 ]
Zhang, Junhao [5 ]
Hu, Daodao [1 ,2 ]
Jin, Pujun [1 ,2 ]
Wang, De-Yi [6 ]
机构：
[1] Shaanxi Normal Univ, Sch Mat Sci & Engn, Xian 710062, Peoples R China
[2] Shaanxi Normal Univ, Engn Res Ctr Hist & Cultural Heritage Protect, Minist Educ, Xian 710062, Peoples R China
[3] South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Peoples R China
[4] Zhejiang Univ, Coll Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Peoples R China
[5] Jiangsu Univ Sci & Technol, Sch Environm & Chem Engn, Zhenjiang 212003, Jiangsu, Peoples R China
[6] IMDEA Mat Inst, C Eric Kandel 2, Madrid 28906, Spain
来源：
PROGRESS IN POLYMER SCIENCE | 2020年 / 108卷
基金：
中国国家自然科学基金; 国家重点研发计划;
关键词：
Bio-based monomeric phenols; Bio-based epoxy thermosets; Epoxy monomers and prepolymers; Epoxy curing agents and additives; Crosslinked network structures; Performances of cured bioepoxy; EPOXIDIZED SOYBEAN OIL; CARDANOL-BASED EPOXY; CASHEW NUT SHELL; LAYERED DOUBLE HYDROXIDE; ANHYDRIDE CURING AGENT; FLAME-RETARDANT; TANNIC-ACID; BISPHENOL-A; DIGLYCIDYL ETHER; BUILDING-BLOCK;
D O I：
10.1016/j.progpolymsci.2020.101287
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Recent years have witnessed significant progress in bio-based epoxy thermosets. A variety of epoxy thermosets have been synthesized from various bioresources. In particular, epoxy thermosets derived from bio-based monomeric phenols, either naturally occurring or biotransformed, such as cardanol, eugenol, vanillin, tannin acid, gallic acid, and so forth. This review summarizes the research regarding this theme and highlights the molecular transformations and ultimate properties of the resultant epoxy thermosets and materials. The relevant epoxy monomers, prepolymers, curing agents, additives, cured thermosets, functional materials and biocomposites are discussed based on their molecular structures and properties of crosslinked networks. Finally, the challenges and opportunities in developing sustainable epoxy thermosets and materials from bio-based monomeric phenols are presented. (c) 2020 Elsevier B.V. All rights reserved.
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页数：46
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