The Rate of Energy Dissipation Determines Probabilities of Non-equilibrium Assemblies

被引：20

作者：

Tretiakov, Konstantin V. ^{[2
]}

Szleifer, Igal ^{[1
]}

Grzybowski, Bartosz A. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Polish Acad Sci, Inst Mol Phys, PL-60179 Poznan, Poland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 39期

关键词：

energy dissipation; entropy production; non-equilibrium; self-assembly; ENTROPY PRODUCTION; DYNAMICS;

D O I：

10.1002/anie.201301386

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Outside thermodynamic equilibrium, outcomes of self-assembly can be dictated not by energy but by the energy dissipation rate. Remarkably, non-equilibrium self-assembly can lead to both low- and high-dissipation structures. The latter, thermodynamically more wasteful structures are exponentially less probable with increasing dissipation rate. This dependence is quantified in a Boltzmann-like relation for non-equilibrium systems. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10304 / 10308

页数：5

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