Investigation into the initialization behaviour of RAFT-mediated styrene-maleic anhydride copolymerizations

被引：32

作者：

van den Dungen, Eric T. A.

Rinquest, Jacques

Pretorius, Nadine O.

McKenzie, Jean M.

McLeary, James B.

Sanderson, Ron D.

Klumperman, Bert ^{[1
]}

机构：

[1] Univ Stellenbosch, Dept Chem & Polymer Sci, UNESCO, Ctr Macromol & Mat, ZA-7602 Matieland, South Africa

[2] Univ Stellenbosch, Cent Analyt Facil, ZA-7602 Matieland, South Africa

[3] Eindhoven Univ Technol, Polymer Chem Lab, NL-5600 MB Eindhoven, Netherlands

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2006年 / 59卷 / 10期

关键词：

D O I：

10.1071/CH06238

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The living radical alternating copolymerization of styrene and maleic anhydride mediated by the reversible addition fragmentation chain transfer (RAFT) polymerization process has been studied at short chain lengths using two different dithiobenzoate RAFT agents. The results indicate specificity of addition of the RAFT-agent leaving groups for either styrene or maleic anhydride. The addition rate of the monomers and the fact that monomers are added individually favour the penultimate unit model of polymer propagation.

引用

页码：742 / 748

页数：7

共 29 条

[1] Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization. I. The current situation [J].

Barner-Kowollik, Christopher ;

Buback, Michael ;

Charleux, Bernadette ;

Coote, Michelle L. ;

Drache, Marco ;

Fukuda, Takeshi ;

Goto, Atsushi ;

Klumperman, Bert ;

Lowe, Andrew B. ;

Mcleary, James B. ;

Moad, Graeme ;

Monteiro, Michael J. ;

Sanderson, Ronald D. ;

Tonge, Matthew P. ;

Vana, Philipp .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (20) :5809-5831

[2] One-step formation of functionalized block copolymers [J].

Benoit, D ;

Hawker, CJ ;

Huang, EE ;

Lin, ZQ ;

Russell, TP .

MACROMOLECULES, 2000, 33 (05) :1505-1507

[3]

Brandrup J., 1999, Polymer handbook, VII

[4] Effect of comonomer composition on the controlled free-radical copolymerization of styrene and maleic anhydride by reversible addition-fragmentation chain transfer (RAFT) [J].

Chernikova, E ;

Terpugova, P ;

Bui, CO ;

Charleux, B .

POLYMER, 2003, 44 (15) :4101-4107

[5] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].

Chiefari, J ;

Chong, YK ;

Ercole, F ;

Krstina, J ;

Jeffery, J ;

Le, TPT ;

Mayadunne, RTA ;

Meijs, GF ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1998, 31 (16) :5559-5562

[6] Radical copolymerization of maleic anhydride and substituted styrenes by reversible addition-fragmentation chain transfer (RAFT) polymerization [J].

Davies, MC ;

Dawkins, JV ;

Hourston, DJ .

POLYMER, 2005, 46 (06) :1739-1753

[7]

De Brouwer H, 2000, J POLYM SCI POL CHEM, V38, P3596, DOI 10.1002/1099-0518(20001001)38:19<3596::AID-POLA150>3.0.CO

[8]

2-F

[9] An ESR study of reversible addition-fragmentation chain transfer copolymerization of styrene and maleic anhydride [J].

Du, FS ;

Zhu, MQ ;

Guo, HQ ;

Li, ZC ;

Li, FM ;

Kamachi, M ;

Kajiwara, A .

MACROMOLECULES, 2002, 35 (17) :6739-6741

[10]

Ha NTH, 1998, ACTA POLYM, V49, P404, DOI 10.1002/(SICI)1521-4044(199808)49:8<404::AID-APOL404>3.0.CO

← 1 2 3 →