Fast pyrolysis of macroalga Saccharina japonica in a bubbling fluidized-bed reactor for bio-oil production

被引：83
作者：
Hoang Vu Ly [1 ]
Kim, Seung-Soo [2 ]
Woo, Hee Chul [3 ]
Choi, Jae Hyung [3 ]
Suh, Dong Jin [4 ]
Kim, Jinsoo [1 ]
机构：
[1] Kyung Hee Univ, Dept Chem Engn, 1732 Deogyeong Daero, Yongin 446701, Gyeonggi Do, South Korea
[2] Kangwon Natl Univ, Dept Chem Engn, Samcheok 245711, Gangwon Do, South Korea
[3] Pukyong Natl Univ, Dept Chem Engn, Busan 608739, South Korea
[4] Korea Inst Sci & Technol, Clean Energy Res Ctr, Seoul 136791, South Korea
来源：
ENERGY | 2015年 / 93卷
关键词：
Bubbling fluidized bed; Fast pyrolysis; Macroalgae; Saccharina japonica; MICROWAVE PYROLYSIS; RENEWABLE FUELS; BIOMASS; KINETICS; LIQUID; BEHAVIOR;
D O I：
10.1016/j.energy.2015.10.011
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Macroalgae have recently attracted attention as a possible feedstock for bio-fuels. Saccharina japonica, a kind of macroalgae, can be converted into bio-oil, gas, and char through pyrolysis. In this study, fast pyrolysis of Saccharina japonica was performed in a bubbling fluidized-bed reactor under various conditions. The effects of pyrolysis temperature and fluidization velocity on product yield and the quality of bio-oil were systematically investigated. When the pyrolysis temperature increased from 350 degrees C to 500 degrees C, the bin-oil yield steadily decreased from 44.99 wt% to 26.67 wt%. The major compounds in the bio-oil were di-anhydromannitol and 2-methyl furyl ketone, showing the highest selectivities of 24.08% and 17.18%, respectively. The C-13 NMR results showed that shorter aliphatic carbon and lower molecular weight compounds of alcohols, ketone, and their derivatives were generated during pyrolysis at higher temperatures due to secondary decomposition reactions. This research showed the feasibility of converting macroalgae biomass into bin-oil by fast pyrolysis. (C) 2015 Elsevier Ltd. All rights reserved.
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收藏
页码：1436 / 1446
页数：11
相关论文
共 43 条
  • [1] Pyrolysis behaviour of the main carbohydrates of brown macro-algae
    Anastasakis, K.
    Ross, A. B.
    Jones, J. M.
    [J]. FUEL, 2011, 90 (02) : 598 - 607
  • [2] The characteristics of bio-oil produced from the pyrolysis of three marine macroalgae
    Bae, Yoon Ju
    Ryu, Changkook
    Jeon, Jong-Ki
    Park, Junhong
    Suh, Dong Jin
    Suh, Young-Woong
    Chang, Daejun
    Park, Young-Kwon
    [J]. BIORESOURCE TECHNOLOGY, 2011, 102 (03) : 3512 - 3520
  • [3] Energy-dense liquid fuel intermediates by pyrolysis of guayule (Parthenium argentatum) shrub and bagasse
    Boateng, Akwasi A.
    Mullen, Charles A.
    Goldberg, Neil M.
    Hicks, Kevin B.
    McMahan, Colleen M.
    Whalen, Maureen C.
    Cornish, Katrina
    [J]. FUEL, 2009, 88 (11) : 2207 - 2215
  • [4] Fast pyrolysis processes for biomass
    Bridgwater, AV
    Peacocke, GVC
    [J]. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2000, 4 (01) : 1 - 73
  • [5] Renewable fuels and chemicals by thermal processing of biomass
    Bridgwater, AV
    [J]. CHEMICAL ENGINEERING JOURNAL, 2003, 91 (2-3) : 87 - 102
  • [6] Principles and practice of biomass fast pyrolysis processes for liquids
    Bridgwater, AV
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 51 (1-2) : 3 - 22
  • [7] A unified correlation for estimating HHV of solid, liquid and gaseous fuels
    Channiwala, SA
    Parikh, PP
    [J]. FUEL, 2002, 81 (08) : 1051 - 1063
  • [8] Analysis of liquid products from biomass via flash pyrolysis
    Demirbas, A
    [J]. ENERGY SOURCES, 2002, 24 (04): : 337 - 345
  • [9] An overview of Biomass pyrolysis
    Demirbas, A
    Arin, G
    [J]. ENERGY SOURCES, 2002, 24 (05): : 471 - 482
  • [10] Dragone G., 2010, Applied Microbiology and Microbial Biotechnology
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