Structure and Reactivity of Late Transition Metal η3-Benzyl Complexes

被引：118

作者：

Trost, Barry M. ^{[1
]}

Czabaniuk, Lara C. ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 11期

基金：

美国国家科学基金会;

关键词：

asymmetric synthesis; homogeneous catalysis; crystallography; transition metals; eta(3)-coordination; CATALYZED NUCLEOPHILIC-SUBSTITUTION; CROSS-COUPLING REACTIONS; H BOND ACTIVATION; HALF-SANDWICH-TYPE; NONRIGID ORGANOMETALLIC MOLECULES; NUCLEAR-MAGNETIC-RESONANCE; PHASE-TRANSFER CATALYSIS; BENZYL HALIDES; OXIDATIVE ADDITION; CRYSTAL-STRUCTURE;

D O I：

10.1002/anie.201305972

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination of transition metals to organic fragments can yield complexes with fascinating and unexpected binding patterns. The study of metal-benzyl complexes has demonstrated the feasibility of eta(3)-coordination, which results in a dearomatized ring. These complexes also offer insight into reaction mechanisms as proposed intermediates in catalytic cycles. In this Review we discuss the synthesis and characterization of these complexes with late transition metals and the subsequent development of catalytic benzylic functionalization methods, including asymmetric variants.

引用

收藏

页码：2826 / 2851

页数：26

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