Hydrates of tin tetrachloride

被引：4

作者：

Genge, ARJ ^{[1
]}

Levason, W ^{[1
]}

Patel, R ^{[1
]}

Reid, G ^{[1
]}

Webster, M ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104005633

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of the tri- and tetrahydrate of tin tetrachloride, viz. diaquatetrachlorotin(IV) monohydrate, [SnCl4(H2O)(2)].H2O, and diaquatetrachlorotin(IV) dihydrate, [SnCl4(H2O)(2)].2H(2)O, are reported and shown to contain the cis-[SnCl4(H2O)(2)] species and water molecules in both cases. The trihydrate contains chains of the tin species linked by a single hydrogen-bonded water molecule, whilst the tetrahydrate has a three-dimensional network. In addition, there are O-H...Cl interactions present.

引用

页码：I47 / I49

页数：3

共 14 条

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