Suppression of dendritic lithium growth in lithium metal-based batteries

被引:192
作者
Li, Linlin [1 ]
Li, Siyuan [1 ]
Lu, Yingying [1 ]
机构
[1] Zhejiang Univ, State Key Lab Chem Engn, Inst Pharmaceut Engn, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China
基金
国家重点研发计划;
关键词
SOLID-ELECTROLYTE INTERPHASE; NANOPARTICLE HYBRID ELECTROLYTES; CATHODE MATERIAL; VOLUME-CHANGE; LIQUID; LAYER; DEPOSITION; ANODE; PULSE; ELECTRODEPOSITION;
D O I
10.1039/c8cc02280a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lithium metal-based batteries offer promising prospects as alternatives to today's lithium-ion batteries, due to their ultra-high energy density. Unfortunately, the application of lithium metal is full of challenges and has puzzled researchers for more than 40 years. In this feature article, we describe the history of the development of lithium metal batteries and their existing key challenges, which include non-uniform electrodeposition, volume expansion, high reactivity of the lithium metal/unstable solid electrolyte interphase (SEI), and the shuttling of active cathode materials. Then, we focus on the growth mechanisms of uneven lithium electrodeposition and extend the discussion to the approaches to inhibit lithium dendrites. Finally, we discuss future directions that are expected to drive progress in the development of lithium metal batteries.
引用
收藏
页码:6648 / 6661
页数:14
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