Hydrothermal liquefaction of Prosopis juliflora biomass for the production of ferulic acid and bio-oil

被引:35
作者
Arun, Jayaseelan [1 ]
Gopinath, Kannappan Panchamoorthy [2 ]
Sivaramakrishnan, Ramachandran [3 ]
Shyam, Sivaprasad [2 ]
Mayuri, Namasivayam [2 ]
Manasa, Sadhasivan [2 ]
Pugazhendhi, Arivalagan [4 ]
机构
[1] Sathyabama Inst Sci & Technol, Ctr Waste Management Int Res Ctr, Chennai 600119, Tamil Nadu, India
[2] Sri Sivasubramaniya Nadar Coll Engn, Dept Chem Engn, Kalavakkam 603110, Tamil Nadu, India
[3] Chulalongkorn Univ, Dept Biochem, Lab Cyanobacterial Biotechnol, Fac Sci, Bangkok 10330, Thailand
[4] Ton Duc Thang Univ, Fac Environm & Labour Safety, Innovat Green Prod Synth & Renewable Environm Dev, Ho Chi Minh City, Vietnam
关键词
Lignocellulosic biomass; Hydrothermal liquefaction; Bio-oil; Vanillin; Ferulic acid; LIQUID-PHASE OXIDATION; RICE HUSK; VANILLIN; WATER; PRETREATMENT; PYROLYSIS; TIO2;
D O I
10.1016/j.biortech.2020.124116
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The objective of this work was to study the hydrothermal liquefaction (HTL) of Prosopis juliflora biomass for the production of ferulic acid and bio-oil. Biomass was processed with various solvents (NaOH, KOH, HCl and H2SO4) to produce ferulic acid (FA). FA oxidation was carried out using the Nano ZnO catalyst to produce an optimum vanillin yield of 0.3 g at 70 degrees C with 0.4% catalyst loading for a time of 60 min. The spent solid residue was then processed using HTL at 5 MPa pressure and a temperature range of 240-340 degrees C. Various biomass loading (2.5 g to 12.5 g) was taken for a fixed water content of 200 mL. Bio-oil optimum yield was 22.5 wt% for 10 g/200 mL of biomass loading ratio. The optimum temperature was 300 degrees C for a processing time of 1 h. The catalyst showed the reusable capability of two three consecutive cycles.
引用
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页数:7
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