Facile Synthesis of High-quality N-doped Graphene Anchored with Fe2O3 for Use As Lithium-ion Battery Anode Materials

被引:0
作者
Yang, Chuanning [1 ]
Qing, Yongquan [1 ]
Shang, Yan [1 ]
Sun, Youzheng [1 ]
Liu, Changsheng [1 ]
机构
[1] Northeastern Univ, Minist Educ, Key Lab Anisotropy & Texture Mat, Shenyang 110004, Liaoning, Peoples R China
关键词
lithium-ion battery; anode materials; graphene; Fe2O3; CAPACITY; ELECTRODES;
D O I
暂无
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A hybrid material composed of nitrogen-doped graphene anchored with Fe2O3 was readily obtained by a facile and one-step hydrothermal method followed by assisting with microwave under mild conditions. Scanning electron microscopy and transmission electron microscopy images show that Fe2O3 with average size of 30-50 nm are homogeneously distributed and anchored on the surface of nitrogen-doped graphene sheets. The N-doped graphene/Fe2O3 hybrid electrodes exhibit excellent electrochemical performance with the charge/discharge capacity maintain stable at around 844.3 mAhg(-1) and 937.7 mAhg(-1) after the 40 th cycle. The enhanced lithium-storage performance is ascribed to the rational design of the hybrid and has a great potential as anode material for lithium ion batteries.
引用
收藏
页码:10651 / 10658
页数:8
相关论文
共 24 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   FILMING MECHANISM OF LITHIUM-CARBON ANODES IN ORGANIC AND INORGANIC ELECTROLYTES [J].
BESENHARD, JO ;
WINTER, M ;
YANG, J ;
BIBERACHER, W .
JOURNAL OF POWER SOURCES, 1995, 54 (02) :228-231
[3]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[4]   Top-Down Fabrication of α-Fe2O3 Single-Crystal Nanodiscs and Microparticles with Tunable Porosity for Largely Improved Lithium Storage Properties [J].
Chen, Jun Song ;
Zhu, Ting ;
Yang, Xiao Hua ;
Yang, Hua Gui ;
Lou, Xiong Wen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (38) :13162-13164
[5]   Porous Fe2O3 nanorods anchored on nitrogen-doped graphenes and ultrathin Al2O3 coating by atomic layer deposition for long-lived lithium ion battery anode [J].
Hu, Tao ;
Xie, Ming ;
Zhong, Jing ;
Sun, Hong-tao ;
Sun, Xiang ;
Scott, Spencer ;
George, Steven M. ;
Liu, Chang-sheng ;
Lian, Jie .
CARBON, 2014, 76 :141-147
[6]   Rapid synthesis of nitrogen-doped graphene for a lithium ion battery anode with excellent rate performance and super-long cyclic stability [J].
Hu, Tao ;
Sun, Xiang ;
Sun, Hongtao ;
Xin, Guoqing ;
Shao, Dali ;
Liu, Changsheng ;
Lian, Jie .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (03) :1060-1066
[7]   Electrochemical impedance of electrolyte/electrode interfaces of lithium-ion rechargeable batteries - Effects of additives to the electrolyte on negative electrode [J].
Itagaki, M ;
Yotsuda, S ;
Kobari, N ;
Watanabe, K ;
Kinoshita, S ;
Ue, M .
ELECTROCHIMICA ACTA, 2006, 51 (8-9) :1629-1635
[8]   Electrodes with high power and high capacity for rechargeable lithium batteries [J].
Kang, KS ;
Meng, YS ;
Bréger, J ;
Grey, CP ;
Ceder, G .
SCIENCE, 2006, 311 (5763) :977-980
[9]  
Kuei C. J., 2010, J MATER CHEM, V20, P3729
[10]   Co3O4@graphene Composites as Anode Materials for High-Performance Lithium Ion Batteries [J].
Li, Baojun ;
Cao, Huaqiang ;
Shao, Jin ;
Li, Guoqiang ;
Qu, Meizhen ;
Yin, Gui .
INORGANIC CHEMISTRY, 2011, 50 (05) :1628-1632