Facile and efficient synthesis of fluorinated fullerene-fused 1,3-dioxolanes: reaction of C60 with fluorinated aromatic aldehyde mediated by lithium perchlorate

被引：5

作者：

Cheng, Hao-Nan ^{[1
]}

Zou, Yuan-Hai ^{[1
]}

Zhang, Jian-Min ^{[1
,2
]}

He, Shan-Shan ^{[1
]}

Shen, Su-Bo ^{[1
]}

Deng, Hong-Mei ^{[3
]}

机构：

[1] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

[3] Shanghai Univ, Ctr Anal & Test, Shanghai 200444, Peoples R China

来源：

TETRAHEDRON | 2014年 / 70卷 / 35期

基金：

中国国家自然科学基金;

关键词：

Fullerene; Lithium perchlorate; Ionic reaction; Fluorine; Cyclic voltammetry; SOLVENT-FREE; AZOMETHINE YLIDES; HYDROXYL-GROUPS; SILYLATION; ACID;

D O I：

10.1016/j.tet.2014.06.038

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of fluorinated fullerene-fused 1,3-dioxolanes have been facilely and efficiently synthesized in the presence of easily available LiClO4 center dot 3H(2)O. The influences of the number of fluoro-substituents and their positions linked to the phenyl ring on the isolated yield of fullerene-fused 1,3-dioxolanes have been studied in detail. Based on reaction facts, a possible reaction mechanism for the formation of fluorinated fullerene-fused 1,3-dioxolanes has been proposed. Furthermore, detailed ultraviolet absorption spectra, fluorescence emission spectra, and cyclic voltammogram further explain the optical properties and electronic transmission capabilities of the products. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：5828 / 5833

页数：6

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