A study on the effect of cenosphere on thermal and ablative behavior of cenosphere loaded ceramic/phenolic composites

被引:20
作者
Balaji, R. [1 ]
Sasikumar, M. [1 ]
机构
[1] VIT Univ, SMBS, Chennai, Tamil Nadu, India
关键词
Thermal stability; Ablative properties; Thermogravimetric analysis (TGA); CARBON/CARBON COMPOSITES; CARBON;
D O I
10.1016/j.polymer.2014.10.037
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Composites of ceramic woven and phenolic resin filled with cenosphere were prepared and their thermal properties and ablative properties were studied by Thermogravimetric Analysis (TGA) and oxyacetylene ablation test. Classical thermal stability parameters, based on initial decomposition temperature and mass loss at various temperatures were calculated before and after subtraction of cenosphere concentration from the TGA curves. Ablation behavior of the filled composites were investigated based on the linear ablation rate, mass ablation rate and back face temperature profiles. Without cenosphere mass subtraction, the thermal stability of the filled composites seems to be improved and reduction of mass loss was achieved with addition of cenosphere. Ablation results showed that the addition of cenosphere content exhibits the favorable ablation resistance. In comparison to neat ceramic/phenolic composites, the introduction of micro sized cenosphere particles embedded in the phenolic matrix significantly improved the ablative properties in terms of mass ablation rate and linear ablation rate. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6634 / 6639
页数:6
相关论文
共 19 条
[1]   Ablation performance and characterization of thermoplastic polyurethane elastomer nanocomposites [J].
Allcorn, Eric K. ;
Natali, Maurizio ;
Koo, Joseph H. .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2013, 45 :109-118
[2]  
[Anonymous], 2008, Annual book of ASTM standards, V15
[3]  
Arijit Das, 2011, MATER DESIGN, V32, P1477
[4]   Correlation of mechanical and tribological properties of organosilane modified cenosphere filled high density polyethylene [J].
Chand, Navin ;
Sharma, Prabhat ;
Fahim, M. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2010, 527 (21-22) :5873-5878
[5]   Mechanical and thermal characteristics of high density polyethylene-fly ash Cenospheres composites [J].
Deepthi, M. V. ;
Sharma, Madan ;
Sailaja, R. R. N. ;
Anantha, P. ;
Sampathkumaran, P. ;
Seetharamu, S. .
MATERIALS & DESIGN, 2010, 31 (04) :2051-2060
[6]  
Knop A., 1985, PHENOLIC RESINS CHEM
[7]   Thermal degradation of phenolic resin/silica hybrid ceramers [J].
Lin, JM ;
Ma, CCM .
POLYMER DEGRADATION AND STABILITY, 2000, 69 (02) :229-235
[8]   Ablative properties of carbon black and MWNT/phenolic composites: A comparative study [J].
Natali, Maurizio ;
Monti, Marco ;
Puglia, Debora ;
Kenny, Jose Maria ;
Torre, Luigi .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2012, 43 (01) :174-182
[9]   A nanostructured ablative bulk molding compound: Development and characterization [J].
Natali, Maurizio ;
Monti, Marco ;
Maria Kenny, Jose ;
Torre, Luigi .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2011, 42 (09) :1197-1204
[10]   Ablation behavior of SiC fiber/carbon matrix composites under simulated atmospheric reentry conditions [J].
Ogasawara, Toshio ;
Aoki, Takuya ;
Hassan, Mohamed Sayed Aly ;
Mizokami, Yosuke ;
Watanabe, Naoyuki .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2011, 42 (03) :221-228