Synthesis and structure of an unprecedented heterometallic tetranuclear cluster [Gd2Co2(μ4-O)(μ-H2O)(CDTA)2(H2O)6]•10H2O (H4CDTA=trans-1,2-cyclohexanedinitrilotetraacetic acid)

被引：37
作者：
Ma, BQ
Gao, S [1 ]
Bai, O
Sun, HL
Xu, GX
机构：
[1] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[2] Peking Univ, PKU HKU Joint Lab Rare Earth Mat & Bioorgan Chem, Beijing 100871, Peoples R China
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 07期
关键词：
D O I：
10.1039/b000490l
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel tetranuclear lanthanide-transition metal cluster [Gd2Co2(mu(4)-O)(mu-H2O)(CDTA)(2)(H2O)(6)]. 10H(2)O has been synthesized, in which the cluster core is held together through mu(4)-O2-, mu-H2O and mu-carboxylate bridges.
引用
收藏
页码：1003 / 1004
页数：2
相关论文
共 35 条
[31]   DECOMPOSITION AND CYCLOADDITION REACTIONS OF HFACAC AND SYNTHESES AND STRUCTURES OF LN(2)(III)(HFACAC)(4)(BDMAP)(2)(H2O)(2)(THF)(2), LN(III)CU(II)(BDMAPH)(2)(HFACAC)(2)(O2CCF3)L, AND LN(III)CU(2)(II)(HFACAC)(BDMAP)(3)(O2CCH3)(2)(O2CCF3)(HFACACH) (LN=Y, PR, ND, HFACAC=HEXAFLUOROACETYLACETONATO, BDMAP=1,3-BIS(DIMETHYLAMINO)-2-PROPANOLATO, L=2-METHYL-2,4,6-TRIS(TRIFLUOROMETHYL)-1,3-DIOXANE-4,6-DIOLATO) [J].
WANG, SN ;
PANG, Z ;
SMITH, KDL ;
HUA, YS ;
DESLIPPE, C ;
WAGNER, MJ .
INORGANIC CHEMISTRY, 1995, 34 (04) :908-917
[32]  
Yang WC, 1996, ACTA CHIM SINICA, V54, P795
[33]   Synthesis and structures of carboxylate-bridged polynuclear copper(II)-lanthanide(III) complexes [CuLn(C5H5N+CH2-CO2-)5(H2O)5][ClO4]5•2H2O (Ln = La or Nd) and [Cu3Nd2(C5H5N+CH2CO2-)10(NO3)2(H2O)8][ClO4]10•4H2O [J].
Yang, YY ;
Wu, YL ;
Long, LS ;
Chen, XM .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (12) :2005-2008
[34]  
Yi T, 1998, POLYHEDRON, V17, P2243
[35]  
Zenobi, UNPUB
1234