Synthesis and structure of an unprecedented heterometallic tetranuclear cluster [Gd2Co2(μ4-O)(μ-H2O)(CDTA)2(H2O)6]•10H2O (H4CDTA=trans-1,2-cyclohexanedinitrilotetraacetic acid)

被引:37
作者
Ma, BQ
Gao, S [1 ]
Bai, O
Sun, HL
Xu, GX
机构
[1] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[2] Peking Univ, PKU HKU Joint Lab Rare Earth Mat & Bioorgan Chem, Beijing 100871, Peoples R China
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 07期
关键词
D O I
10.1039/b000490l
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel tetranuclear lanthanide-transition metal cluster [Gd2Co2(mu(4)-O)(mu-H2O)(CDTA)(2)(H2O)(6)]. 10H(2)O has been synthesized, in which the cluster core is held together through mu(4)-O2-, mu-H2O and mu-carboxylate bridges.
引用
收藏
页码:1003 / 1004
页数:2
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