Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex

被引：30

作者：

Faulmann, Christophe ^{[1
]}

Szilagyi, Petra A. ^{[1
]}

Jacob, Kane ^{[1
]}

Chahine, Joe ^{[1
]}

Valade, Lydie ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

NEW JOURNAL OF CHEMISTRY | 2009年 / 33卷 / 06期

关键词：

ELECTRICAL-CONDUCTIVITY; MOLECULAR MATERIALS; THERMAL HYSTERESIS; CRYSTAL-STRUCTURE; TRANSITION; PRESSURE; TEMPERATURE; LIGHT; STATE;

D O I：

10.1039/b901779h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses, structural characterisation, and magnetic and spectroscopic properties of three new polymorphs of the spin-crossover complex [Fe(sal(2)-trien)][Ni(dmit)(2)] are reported. The results are discussed as a function of their intra- and intermolecular arrangement. Correlation of their crystal structures and magnetic properties suggest that some torsion angles play a significant role in the magnetic properties of this class of compounds. Intermolecular contacts are also of importance, and the nature of the short contacts between molecular species seems to be more crucial than their number in the allowance of spin-crossover.

引用

页码：1268 / 1276

页数：9

共 50 条

[41] Heteroleptic FeII Complexes of 2,2′-Biimidazole and Its Alkylated Derivatives: Spin-Crossover and Photomagnetic Behavior
Phan, Hoa V.
Chakraborty, Pradip
Chen, Meimei
Calm, Yitzi M.
Kovnir, Kirill
Keniley, Lawrence K., Jr.
Hoyt, Jordan M.
Knowles, Elisabeth S.
Besnard, Celine
Meisel, Mark W.
Hauser, Andreas
Achim, Catalina
Shatruk, Michael
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (49) : 15805 - 15815
[42] [Fe(nsal2trien)]SCN, a New Two-Step Iron(III) Spin Crossover Compound, with Symmetry Breaking Spin-State Transition and an Intermediate Ordered State
Vieira, Bruno J. C.
Coutinho, Joana T.
Santos, Isabel C.
Pereira, Laura C. J.
Waerenborgh, Joao C.
da Gama, Vasco
INORGANIC CHEMISTRY, 2013, 52 (07) : 3845 - 3850
[43] Crystal structure and magnetic properties of the spin crossover complex FeII(ethyl nicotinate)2[AuI(CN)2]2
Sugaya, Akihiro
Ueno, Shotaro
Okabayashi, Jun
Kitazawa, Takafumi
NEW JOURNAL OF CHEMISTRY, 2014, 38 (05) : 1955 - 1958
[44] Piezoresistive Effect in the [Fe(Htrz)2(trz)](BF4) Spin Crossover Complex
Diaconu, Andrei
Lupu, Simona-Lacramioara
Rusu, Ionela
Risca, Ioan-Marian
Salmon, Lionel
Molnar, Gabor
Bousseksou, Azzedine
Demont, Philippe
Rotaru, Aurelian
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (13): : 3147 - 3151
[45] A novel two-step Fe-Au type spin-crossover behavior in a Hofmann-type coordination complex {Fe(4-methylpyrimidine)2[Au(CN)2]2}
Kitase, Kosuke
Kitazawa, Takafumi
DALTON TRANSACTIONS, 2020, 49 (35) : 12210 - 12214
[46] Structure of a spin-crossover Fe(II)-1,2,4-triazole polymer complex gel in toluene. Small angle neutron scattering and viscoelastic studies
Echeverria, Coro
Rubio, Miguel
Mitchell, Geoffrey R.
Lopez, Daniel
EUROPEAN POLYMER JOURNAL, 2014, 53 : 238 - 245
[47] A luminescent Pt2Fe spin crossover complex
Schaefer, Bernhard
Bauer, Thomas
Faus, Isabelle
Wolny, Juliusz A.
Dahms, Fabian
Fuhr, Olaf
Lebedkin, Sergei
Wille, Hans-Christian
Schlage, Kai
Chevalier, Katharina
Rupp, Fabian
Diller, Rolf
Schuenemann, Volker
Kappesa, Manfred M.
Ruben, Mario
DALTON TRANSACTIONS, 2017, 46 (07) : 2289 - 2302
[48] Thermally and photo-induced spin crossover behaviour in an Fe(II) imidazolylimine complex: [FeL3](ClO4)2
Thompson, John R.
Archer, Rosanna J.
Hawes, Chris S.
Ferguson, Alan
Wattiaux, Alain
Mathoniere, Corine
Clerac, Rodolphe
Kruger, Paul E.
DALTON TRANSACTIONS, 2012, 41 (41) : 12720 - 12725
[49] Density functional plus dynamical mean-field theory of the spin-crossover molecule Fe(phen)2(NCS)2
Chen, Jia
Millis, Andrew J.
Marianetti, Chris A.
PHYSICAL REVIEW B, 2015, 91 (24):
[50] Auxiliary alkyl chain modulated spin crossover behaviour of [Fe(H2Bpz2)2(Cn-bipy)] complexes
Guo, Yunnan
Rotaru, Aurelian
Mueller-Bunz, Helge
Morgan, Grace G.
Zhang, Shishen
Xue, Shufang
Garcia, Yann
DALTON TRANSACTIONS, 2021, 50 (37) : 12835 - 12842

← 1 2 3 4 5 →