Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex

被引：30

作者：

Faulmann, Christophe ^{[1
]}

Szilagyi, Petra A. ^{[1
]}

Jacob, Kane ^{[1
]}

Chahine, Joe ^{[1
]}

Valade, Lydie ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

NEW JOURNAL OF CHEMISTRY | 2009年 / 33卷 / 06期

关键词：

ELECTRICAL-CONDUCTIVITY; MOLECULAR MATERIALS; THERMAL HYSTERESIS; CRYSTAL-STRUCTURE; TRANSITION; PRESSURE; TEMPERATURE; LIGHT; STATE;

D O I：

10.1039/b901779h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses, structural characterisation, and magnetic and spectroscopic properties of three new polymorphs of the spin-crossover complex [Fe(sal(2)-trien)][Ni(dmit)(2)] are reported. The results are discussed as a function of their intra- and intermolecular arrangement. Correlation of their crystal structures and magnetic properties suggest that some torsion angles play a significant role in the magnetic properties of this class of compounds. Intermolecular contacts are also of importance, and the nature of the short contacts between molecular species seems to be more crucial than their number in the allowance of spin-crossover.

引用

页码：1268 / 1276

页数：9

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