Nanoenergetic materials: boron nanoparticles from the pyrolysis of decaborane and their functionalisation

被引：65

作者：

Bellott, Brian J. ^{[1
]}

Noh, Wontae ^{[1
]}

Nuzzo, Ralph G. ^{[1
]}

Girolami, Gregory S. ^{[1
]}

机构：

[1] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 22期

关键词：

CHEMICAL-VAPOR-DEPOSITION; THIN-FILMS; COMBUSTION; PARTICLES; DIBORANE; IGNITION;

D O I：

10.1039/b902371b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The surfaces of boron nanoparticles 10-150 nm in diameter, prepared by gas phase pyrolysis of decaborane vapour at 1 atm and 700-900 degrees C, can be halogenated by treatment with Br-2 or XeF2; the surface halogenation somewhat increases the onset temperature for the oxidation of the particles under O-2.

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收藏

页码：3214 / 3215

页数：2

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