Pyrolysis of glycerol over activated carbons for syngas production

被引：127

作者：

Fernandez, Y. ^{[1
]}

Arenillas, A. ^{[1
]}

Diez, M. A. ^{[1
]}

Pis, J. J. ^{[1
]}

Menendez, J. A. ^{[1
]}

机构：

[1] CSIC, Inst Nacl Carbon, E-33080 Oviedo, Spain

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2009年 / 84卷 / 02期

关键词：

Glycerol; Microwave; Activated carbon; Syngas; BIOMASS-DERIVED HYDROCARBONS; MODIFIED NI CATALYSTS; HYDROGEN-PRODUCTION; OXYGENATED HYDROCARBONS; SUPERCRITICAL WATER; METAL-CATALYSTS; STEAM; CONVERSION; MICROWAVE; GAS;

D O I：

10.1016/j.jaap.2009.01.004

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The pyrolysis of glycerol was carried out over carbonaceous catalysts to produce synthesis gas (up to 81 vol.%). The catalytic effect of two activated carbons was tested and compared with quartz glass chips as packing materials in a fixed-bed reactor. The main advantage of using a carbonaceous catalyst seems to be its higher selectivity toward hydrogen, resulting in a synthesis gas with a greater H-2/CO ratio. The influence of the heating method (electrical furnace and microwave oven) and temperature (from 400 to 900 degrees C) on the pyrolysis of glycerol over a selected activated carbon was also studied. As a result, an elevated gas fraction with a higher H-2 + CO Composition was obtained under microwave heating, even at low temperatures. This proves that microwave heating could be used to upgrade the industrial surplus generated from bio-diesel production. (c) 2009 Elsevier B.V. All rights reserved.

引用

页码：145 / 150

页数：6

共 43 条

[1] A comparative thermodynamic and experimental analysis on hydrogen production by steam reforming of glycerin [J].