Nonprecious Metals Catalyzing Hydroamination and C-N Coupling Reactions

被引：81

作者：

Coman, Simona M. ^{[1
]}

Parvulescu, Vasile I. ^{[1
]}

机构：

[1] Univ Bucharest, Fac Chem, Dept Organ Chem Biochem & Catalysis, Bucharest 030016, Romania

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2015年 / 19卷 / 10期

关键词：

ANTI-MARKOVNIKOV HYDROAMINATION; ASYMMETRIC-CONJUGATE REDUCTION; EFFICIENT COPPER CATALYST; ALKYNE 2+2 CYCLOADDITIONS; ALKALINE-EARTH CATALYSTS; INTERMOLECULAR HYDROAMINATION; INTRAMOLECULAR HYDROAMINATION; ARYL HALIDES; HIGHLY EFFICIENT; CARBON-HETEROATOM;

D O I：

10.1021/acs.oprd.5b00010

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This review highlights the recent achievements in replacing precious-metal-based catalysts with nonprecious-metal-based catalysts in two important syntheses: hydroamination and C-N coupling reactions. The reported improvements are discussed in direct relation to the nature of the ligands, catalyst preparation methods, and the selection of other additives. Syntheses using ligand-free catalysts are also analyzed.

引用

页码：1327 / 1355

页数：29

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