Catalytic C-H Oxidation Enhances Polyethylene Bonding

被引:10
|
作者
Musolino, Stefania F. [1 ]
Wulff, Jeremy E. [1 ]
机构
[1] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
来源
CHEM | 2021年 / 7卷 / 01期
关键词
HYDROXYLATION;
D O I
10.1016/j.chempr.2020.12.019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Selectively adding functionality to commodity plastics is an abiding challenge in polymer science. In this issue of Chem, Hartwig and co-workers describe a selective, catalytic oxidation of polyethylene C-H bonds by using high-valent ruthenium-oxo species. The transformation increases polyethylene's adhesive properties without significantly modifying its thermal stability or mechanical strength.
引用
收藏
页码:7 / 9
页数:4
相关论文
共 50 条
  • [1] Catalytic C-H oxidation by a triazamacrocyclic ruthenium complex
    McNeill, Eric
    Du Bois, J.
    CHEMICAL SCIENCE, 2012, 3 (06) : 1810 - 1813
  • [2] Selective Catalytic Oxidation of C-H Bonds with Molecular Oxygen
    Roduner, Emil
    Kaim, Wolfgang
    Sarkar, Biprajit
    Urlacher, Vlada B.
    Pleiss, Juergen
    Glaeser, Roger
    Einicke, Wolf-Dietrich
    Sprenger, Georg A.
    Beifuss, Uwe
    Klemm, Elias
    Liebner, Christian
    Hieronymus, Hartmut
    Hsu, Shih-Fan
    Plietker, Bernd
    Laschat, Sabine
    CHEMCATCHEM, 2013, 5 (01) : 82 - 112
  • [3] Development of Catalytic Site-Selective C-H Oxidation
    Uchida, Tatsuya
    CHEMICAL RECORD, 2023, 23 (11)
  • [4] Influence of Solvents on Catalytic C-H Bond Oxidation by a Copper(II)-Alkylperoxo Complex
    Lee, Yuri
    Kim, Bohee
    Kim, Seonghan
    Ng, Elvis Wang Hei
    Ariyasu, Shinya
    Shoji, Osami
    Yoon, Sungho
    Hirao, Hajime
    Cho, Jaeheung
    ACS CATALYSIS, 2024, 14 (05) : 3524 - 3532
  • [5] Molecular Dynamics of Dimethyldioxirane C-H Oxidation
    Yang, Zhongyue
    Yu, Peiyuan
    Houk, K. N.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (12) : 4237 - 4242
  • [6] Cationic Nickel(II) Pyridinophane Complexes: Synthesis, Structures and Catalytic Activities for C-H Oxidation
    Nishimura, Tsubasa
    Ando, Yuki
    Shinokubo, Hiroshi
    Miyake, Yoshihiro
    CHEMISTRY LETTERS, 2021, 50 (05) : 1049 - 1052
  • [7] Progress in Catalytic C-H Activation Reactions in Water
    Yang, Jun
    Fu, Ting
    Long, Yang
    Zhou, Xiangge
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (05) : 1111 - 1116
  • [8] Scalable, Electrochemical Oxidation of Unactivated C-H Bonds
    Kawamata, Yu
    Yan, Ming
    Liu, Zhiqing
    Bao, Deng-Hui
    Chen, Jinshan
    Starr, Jeremy T.
    Baran, Phil S.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (22) : 7448 - 7451
  • [9] Understanding Catalytic Enantioselective C-H Bond Oxidation at Nonactivated Methylenes Through Predictive Statistical Modeling Analysis
    Call, Arnau
    Palone, Andrea
    Liles, Jordan P.
    Romer, Natalie P.
    Read, Jacquelyne A.
    Luis, Josep M.
    Sigman, Matthew S.
    Bietti, Massimo
    Costas, Miquel
    ACS CATALYSIS, 2025, 15 (03): : 2110 - 2123
  • [10] Catalytic and stoichiometric C-H oxidation of benzylalcohols and hydrocarbons mediated by nonheme oxoiron(IV) complex with chiral tetrapyridyl ligand
    Lakk-Bogath, Dora
    Kripli, Balazs
    Meena, Bashdar I.
    Speier, Gabor
    Kaizer, Jozsef
    INORGANIC CHEMISTRY COMMUNICATIONS, 2019, 104 : 165 - 170